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A Thermoanalytical Study of Mixtures of Polyvinyl Alcohol with Succinic Acid after Plastic Deformation under High Pressure

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Abstract

Mixtures of polyvinyl alcohol and amber acid of different composition were subjected to plastic deformation under the pressure of 1.5 GPa at the equipment of the Bridgman-anvil type and the DSC method was used to study heat processes in nondeformed and deformed samples. It is shown that two processes occur simultaneously in PVA under heating: the endothermal process of decomposition of intermolecular bonds and mass decrease related to loss of adsorbed water. After plastic deformation, a decrease in the enthalpy of melting occurred in both components of the PVC–amber-acid mixtures. A low-temperature phase with Tmelt 30–40° C lower than in the initial polymer was formed in the acid and a decrease in the relaxation process enthalpy was observed in the polymer.

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Authors and Affiliations

  1. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia

    V. A. Zhorin

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 117915, Russia

    M. R. Kiselev & V. A. Kotenev

Authors
  1. V. A. Zhorin
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  2. M. R. Kiselev
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  3. V. A. Kotenev
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Correspondence to V. A. Zhorin.

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Zhorin, V.A., Kiselev, M.R. & Kotenev, V.A. A Thermoanalytical Study of Mixtures of Polyvinyl Alcohol with Succinic Acid after Plastic Deformation under High Pressure. Prot Met Phys Chem Surf 53, 1075–1081 (2017). https://doi.org/10.1134/S2070205117060247

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  • DOI: https://doi.org/10.1134/S2070205117060247

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