Skip to main content
SpringerLink
Log in

The influence of alkaline treatment on the chemical composition and adsorption-structural characteristics of mineral nanoporous sorbent M45K20

  • Nanoscale and Nanostructured Materials and Coatings
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

The chemical and adsorption-structural properties of natural nanoporous mineral sorbent M45C20 having two main components (clay-montmorillonite and zeolite-clinoptilolite) and treated with 2M NaOH solution are investigated. It is ascertained based on the results of chemical analysis, X-ray diffraction, electron microscopy, and IR spectrometry that alkali treatment results in modification of the chemical composition and structure of the mineral sorbent M45C20 and significantly improves its adsorption properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Tarasevich, Yu.I. and Ovcharenko, F.D., Adsorbtsiya na glinistykh mineralakh (Adsorption on Clay Minerals), Kiev: Naukova Dumka, 1975.

    Google Scholar 

  2. Tsitsishvili, G.V., Andronikashvili, T.G., Kirov, G.N., and Filizova, L.D., Prirodnye tseolity (Natural Zeolites), Moscow: Khimiya, 1985.

    Google Scholar 

  3. Goncharuk, V.V., Biba, A.D., Buntova, M.A., and Nasonovich, A.A., Abstracts of Papers, Sbornik dokladov Respublikanskoi nauchno-practicheskoi konferentsii (Proc. Republican Scientific-Practical Conf.), Cherkassy, 1991, p. 26.

  4. Moronta, A., Luengo, J., Ramirez, Y., et al., Appl. Clay Sci., 2005, vol. 29, p. 117.

    Article  CAS  Google Scholar 

  5. Neaman, A., Pelletier, M., and Villieras, F., Appl. Clay. Sci., 2003, vol. 22, p. 153.

    Article  CAS  Google Scholar 

  6. Sprynskyy, M., Lebedynets, M., Zbytniewski, R., and Namiesnik, J., Sep. Purif. Technol., 2005, vol. 46, no. 3, p. 155.

    Article  CAS  Google Scholar 

  7. Rozic, M., Cerjan-Stefanovic, S., Kurajica, S., et al., Water Res., 2000, vol. 34, no. 14, p. 3675.

    Article  CAS  Google Scholar 

  8. Akimova, M.K., Cand. Sci. (Chem) Dissertation, Frunze, 1973.

  9. Zhdanov, S.P. and Egorova, E.N., Khimiya tseolitov (Zeolite Chemistry), Leningrad: Nauka, 1968.

    Google Scholar 

  10. Brek. D., Tseolitovye molekulyarnye sita (Zeolite Molecular Sieves), Moscow: Mir, 1976.

    Google Scholar 

  11. Komarov, V.S., Adsorbenty: poluchenie, struktura, svoistva (Production, Structure and Properties of Adsorbents), Minsk: Belarus. Navuka, 2009.

    Google Scholar 

  12. Mdivnishvili, O.M., Kristallokhimicheskie osnovy regulirovaniya svoistv prirodnykh sorbentov (Crystallochemical Foundations of Controlling the Properties of Natural Sorbents), Tbilisi: Metsniereba, 1978.

    Google Scholar 

  13. Mikhailova, O.A. and Lygina, T.Z., Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 2, p. 231–238.

    Article  CAS  Google Scholar 

  14. Bel’chinskaya, L.I., Khodosova, N.A., and Bityutskaya, L.A., Prot. Met. Phys. Chem. Surf., 2009, vol. 45, no. 2, pp. 203–206.

    Article  Google Scholar 

  15. Khodosova, N.A., Belchinskaya, L.I., Petukhova, G.A., and Voishcheva, O.V., Prot. Met. Phys. Chem. Surf., 2010, vol. 46, no. 1, pp. 90–95.

    Article  CAS  Google Scholar 

  16. Bel’chinskaya, L.I. and Novikova, L.A., Sorb. Khromatogr. Protsessy, vol. 7, no. 5, p. 741.

  17. Bogdanova, V.I., Opredelenie ionoobmennoi emkosti tseolitsoderzhashchei porody po summe vytesnennykh iz nee obmennykh kationov. Instruktsiya 25. Komitet RF po geologii i ispol’zovaniyu nedr (Ion-Exchange Capacity Determination of Zeolite-Containing Rock by Total Exchange Cations Being Replaced. Instruction No. 25. RF Committee for Geology and the Use of Subsurface Resources), Novosibirsk: NSOMMI, 1993.

    Google Scholar 

  18. Katorgina, E.M., Kynin, A.T., Lysenko, A.A., and Teploukhova, M.V., Metodicheskie ukazaniya k vypolneniyu uchebno-issledovatel’skoi raboty po fizicheskoi i kolloidnoi khimii (Methodological Instructive Regulations on Performing Education-Research Work on Physical and Colloidal Chemistry), St. Petersburg, 1995.

  19. Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Foundations of Adsorption Technique), Moscow: Khimiya, 1984.

    Google Scholar 

  20. Ovcharenko, F.D., Gidrofil’nost’ glin i glinistykh mineralov (Hydrophility of Clays and Clay Minerals), Kiev: AN USSR, 1961.

    Google Scholar 

  21. Tarasevich, Yu.I., Stroenie i khimiya poverkhnosti sloistykh silikatov (Structure and the Surface Chemistry of Laminar Silicates), Kiev: Naukova Dumka, 1988.

    Google Scholar 

  22. Kiselev, A.V. and Lygin, V.I., Infrakrasnye spektry poverkhnostnykh soedinenii (Infrared Spectra of Surface Compounds), Moscow: Nauka, 1972.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Voronezh State Forestry Engineering Academy, ul. Timiryazeva 8, Voronezh, 394087, Russia

    L. I. Bel’chinskaya & O. V. Voishcheva

  2. Voronezh State University, Universitetskaya pl. 1, Voronezh, 394006, Russia

    V. Yu. Khokhlov, T. Y. Lu & A. V. Zhabin

  3. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii prospekt 31, Moscow, 119991, Russia

    G. A. Petukhova

Authors
  1. L. I. Bel’chinskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Yu. Khokhlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. Y. Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. A. Petukhova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. V. Voishcheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. V. Zhabin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. I. Bel’chinskaya.

Additional information

Original Russian Text © L.I. Bel’chinskaya, V.Yu. Khokhlov, T.Y. Lu, G.A. Petukhova, O.V. Voishcheva, A.V. Zhabin, 2012, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2012, Vol. 48, No. 3, pp. 274–279.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bel’chinskaya, L.I., Khokhlov, V.Y., Lu, T.Y. et al. The influence of alkaline treatment on the chemical composition and adsorption-structural characteristics of mineral nanoporous sorbent M45K20 . Prot Met Phys Chem Surf 48, 322–327 (2012). https://doi.org/10.1134/S2070205112030033

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205112030033

Keywords

Search

Navigation