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New efficient method for activation of dormant chains in pseudoliving radical polymerization

  • Polymerization
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Abstract

With the use of the competitive inhibition method and ESR spectroscopy, it is shown that, in pseudoliving radical polymerization, the rate constant of decomposition of PS and poly(acrylic acid) adducts with nitroxide radicals significantly increases as the polarity of a medium increases. This phenomenon opens a new approach to the activation of chains in nitroxide-mediated polymerization.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    O. V. Borisova, M. Yu. Zaremski & V. B. Golubev

  2. Equipe de Physique et Chimie des Polymères UPPA, CNRS UMR 5254 IPREM, Pau, France

    O. V. Borisova, O. V. Borisov & L. Billon

  3. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31, St. Petersburg, 199004, Russia

    O. V. Borisov

Authors
  1. O. V. Borisova
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  2. M. Yu. Zaremski
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  3. V. B. Golubev
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  4. O. V. Borisov
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  5. L. Billon
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Corresponding author

Correspondence to M. Yu. Zaremski.

Additional information

Original Russian Text © O.V. Borisova, M.Yu. Zaremski, V.B. Golubev, O.V. Borisov, L. Billon, 2011, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2011, Vol. 53, No. 7, pp. 1139–1141.

This work was supported by the Russian Foundation for Basic Research (project no. 08-03-00269a) and Conseil régional d’Aquitaine.

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Borisova, O.V., Zaremski, M.Y., Golubev, V.B. et al. New efficient method for activation of dormant chains in pseudoliving radical polymerization. Polym. Sci. Ser. B 53, 409 (2011). https://doi.org/10.1134/S1560090411060017

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  • DOI: https://doi.org/10.1134/S1560090411060017

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