Abstract
A procedure has been developed for the conversion of the CS gas [2-(2-chlorobenzylidene)-malononitrile] to new 3-cyanocoumarin derivatives, 4-(2-chlorophenyl)-2-oxo-2H-chromene-3-carbonitriles. Study of the optical properties of the synthesized compounds has revealed strong fluorescence in the violet and blue regions.
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Fourati, M.A., Maris, Th., Skene, W.G., Bazuin, C.G., and Prud’homme, R.E., J. Phys. Chem. B, 2011, vol. 115, p. 12362.
The Chemistry of Synthetic Dyes, Venkataraman, K., Ed., New York: Academic, 1971, vol. 5, p. 535.
Jones, G. and Rahman, M.A., J. Phys. Chem., 1994, vol. 98, p. 13028.
Vemula, V., Ni, Zh., and Fedorova, M., Redox Biol., 2015, vol. 5, p. 195.
Kontogiorgis, Ch.A. and Hadjipavlou-Litina, D.J., J. Med. Chem., 2005, vol. 48, p. 6400.
Witaicenis, A., Seito, L.N., da Silveira Chagas, A., de Almeida, L.D., Luchini, A.C., Rodrigues-Orsi, P., Cestari, S.H., and Di Stasi, L.C., Phytomedicine, 2014, vol. 21, p. 240.
Keri, R.S., Sasidhar, B.S., Nagaraja, B.M., and Santos, M.A., Eur. J. Med. Chem., 2015, vol. 100, p. 257.
Coumarin Anticoagulant Research Progress, Edardes, J.P., Ed., New York: Nova Biomedical Books, 2008.
Bardasov, I.N., Alekseeva, A.U., Ershov, O.V., Surazhskaya, M.D., Churakov, A.V., and Grishanov, D.A., Tetrahedron Lett., 2015, vol. 56, p. 6145.
Kolla, S.R. and Lee, Y.R., Tetrahedron, 2011, vol. 67, p. 8271.
Bauchinger, M. and Schmid, E., Mutat. Res., 1992, vol. 282, p. 231.
Dekamin, M.G., Eslami, M., and Maleki, A., Tetrahedron, 2013, vol. 69, p. 1074.
Han, G., Du, J., Chen, L., and Zhao, L., J. Heterocycl. Chem., 2014, vol. 51, p. 1094.
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Original Russian Text © I.N. Bardasov, N.L. Malyshkina, A.Yu. Alekseeva, O.V. Ershov, D.V. Timrukova, A.O. Grigor’eva, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 1, pp. 53–55.
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Bardasov, I.N., Malyshkina, N.L., Alekseeva, A.Y. et al. Synthesis and optical properties of new coumarin derivatives based on 2-(2-chlorobenzylidene)malononitrile. Russ J Org Chem 53, 47–50 (2017). https://doi.org/10.1134/S1070428017010080
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DOI: https://doi.org/10.1134/S1070428017010080