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Stereoselective synthesis of allylamines by iron-catalyzed cross-coupling of 3-chloroprop-2-en-1-amines with grignard reagents. Synthesis of naftifine

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Abstract

A general procedure for the synthesis of trans- and cis-allylamines has been developed on the basis of iron-catalyzed cross-coupling of Grignard reagents with stereochemically pure 3-chloroprop-2-en-1-amines prepared by allylation of amines with commercially available 1,3-dichloropropene isomers.

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Authors and Affiliations

  1. Ufa State Petroleum Technological University, ul. Kosmonavtov 1, Ufa, 450062, Bashkortostan, Russia

    R. N. Shakhmaev, A. Sh. Sunagatullina & V. V. Zorin

Authors
  1. R. N. Shakhmaev
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  2. A. Sh. Sunagatullina
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  3. V. V. Zorin
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Correspondence to R. N. Shakhmaev.

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Original Russian Text © R.N. Shakhmaev, A.Sh. Sunagatullina, V.V. Zorin, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 3, pp. 334–342.

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Shakhmaev, R.N., Sunagatullina, A.S. & Zorin, V.V. Stereoselective synthesis of allylamines by iron-catalyzed cross-coupling of 3-chloroprop-2-en-1-amines with grignard reagents. Synthesis of naftifine. Russ J Org Chem 50, 322–331 (2014). https://doi.org/10.1134/S1070428014030038

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  • DOI: https://doi.org/10.1134/S1070428014030038

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