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Effect of the Structure of Phosphoryl-Containing Podands on the Extraction of Actinides and Lanthanides(III) from Nitric Acid Solutions

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Abstract

The extraction of U(VI), Th(IV), Am(III), and lanthanide(III) ions and HNO3 from nitric acid solutions with 1,2-dichloroethane solutions of 3-oxapentane-1,5-diylbis(diphenylphosphine)dioxide and its structural analogues was studied. The stoichiometry of the extractable complexes was determined. The effects of the extractant structure and HNO3 concentration in the aqueous phase on the efficiency of the metal ions extraction into the organic phase were considered. The successive replacement of two methylene groups connecting the ether oxygen atom with Ph2P(O) groups in the podand molecule by o-phenylene groups leads to an increase in the efficiency of Th(IV) Am(III), and Ln(III) extraction from nitric acid solutions, but has little effect on the efficiency of U(VI) extraction.

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Funding

The work was carried out within the framework of the state task for 2022 of Yu.A. Osipyan Institute of Solid State Physics, the Institute of Microelectronics Technology and Highly Pure Materials of RAS, the Institute of Physiologically Active Substances of RAS, and A.N. Frumkin Institute of Physical Chemistry and Electrochemistry of RAS.

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Correspondence to D. V. Baulin.

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Turanov, A.N., Karandashev, V.K., Baulin, V.E. et al. Effect of the Structure of Phosphoryl-Containing Podands on the Extraction of Actinides and Lanthanides(III) from Nitric Acid Solutions. Russ J Gen Chem 92, 2290–2296 (2022). https://doi.org/10.1134/S1070363222110135

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