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Synthesis and Properties of Dimercury(I) Crystal Network Constructed with Functionalized Pyrazine Sulfonate and Nitrate Linkers

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Abstract

Coordination nature in the structures between the heterocyclic sulfonic acid group and heavy metal atoms, structural optimization, their physical and chemical properties have been studied. Herein, a new compound [Hg2(P–SO3)(NO3)]n (1) has been synthesized via solvent volatilization method, according to which pyrazine sulfonic acid (P–SO3H) has been used as the major ligand, and nitrate has been used as the precursor. X-Ray single-crystal diffraction analysis demonstrates that 1 belongs to the Pca21 space group. Both pyrazine sulfonate and nitrate serve as chelate bridging linkers for the dimercury(I) ions (Hg22+or HgI–HgI) forming the 2D layer coordination polymer involved in further construction of the stable 3D network through the π–π stacking of pyrazine rings. Thermal stability and fluorescence properties of 1 have been closely studied.

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Notes

  1. Crystallographic data for the structural analysis have been deposited at the Cambridge Crystallographic Data Center with CCDC 1995512 for [Hg2(P–SO3)(NO3)]n (P–SO3=pyrazine sulfonic acid). Copies of this information may be obtained free of charge from the CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (Fax: +44 1223 336 033; E-mail: deposit@ccdc.cam.ac.uk or www.ccdc.cam.ac.uk).

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Funding

The research was supported by the Key scientific research projects in Colleges and Universities of Henan province (no. 21A150036), the National Undergraduate Training Program for Innovation and Entrepreneurship (no. 20181184701) and the Scientific Research Program of High-Level Talents of Foshan University (no. Gg07118).

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Authors and Affiliations

  1. School of Medicine, Foshan University, 528000, Foshan, China

    H. Hu, J. Quan, Z. Tan, J.-H. Fu & Y.-J. Liang

  2. Henan Key Laboratory of Function-Oriented Porous Materials, College of Chemistry and Chemical Engineering, Luoyang Normal University, 471934, Luoyang, China

    J.-X. Li

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  1. H. Hu
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  2. J. Quan
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  3. Z. Tan
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  4. J.-H. Fu
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  5. Y.-J. Liang
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Correspondence to Y.-J. Liang or J.-X. Li.

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Hu, H., Quan, J., Tan, Z. et al. Synthesis and Properties of Dimercury(I) Crystal Network Constructed with Functionalized Pyrazine Sulfonate and Nitrate Linkers. Russ J Gen Chem 91, 910–914 (2021). https://doi.org/10.1134/S1070363221050224

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