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[Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure

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Abstract

The complex [Re(CO)3(bipy)(ClO4)] (bipy = 2,2ʹ-bipyridine) was prepared by the reaction of [Re(CO)3(H2O,EtOH)3](ClO4) with bipy in aqueous ethanol, followed by crystallization from dichloromethane. The composition and structure of the complex were determined by single crystal X-ray diffraction analysis. The complex has a molecular octahedral structure with bidentate coordination of bipy and inner-sphere monodentate coordination of perchlorate ion in the fac-position to bipy. The complex was also characterized by IR and UV-visible absorption spectroscopy.

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Funding

The study was performed with financial support of Russian Foundation for Basic Research (project no. 19-33-90040\19).

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Authors and Affiliations

  1. Khlopin Radium Institute, 194021, St. Petersburg, Russia

    A. E. Miroslavov, G. V. Sidorenko & M. Yu. Tyupina

  2. St. Petersburg State University, 199034, St. Petersburg, Russia

    A. E. Miroslavov, M. Yu. Tyupina & V. V. Gurzhiy

Authors
  1. A. E. Miroslavov
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  2. G. V. Sidorenko
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  3. M. Yu. Tyupina
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  4. V. V. Gurzhiy
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Correspondence to A. E. Miroslavov.

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Miroslavov, A.E., Sidorenko, G.V., Tyupina, M.Y. et al. [Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure. Russ J Gen Chem 90, 2333–2337 (2020). https://doi.org/10.1134/S1070363220120178

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  • DOI: https://doi.org/10.1134/S1070363220120178

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