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Decomposition of Benzoyl Peroxide in the Presence of Ferrocene

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Abstract

Decomposition of benzoyl peroxide in the presence of ferrocene has been shown to proceed simultaneously via several pathways—thermal decomposition, the decomposition catalyzed by iron ions, and the reaction with ferrocene with the formation of ferrocenium radical-cation.

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Funding

This study was performed in the scope of the research topic of UIC RAS, no. AAAA-A17-117011910035-5. The authors acknowledge the Center for Collective Usage “Chemistry” of UIC RAS for providing the opportunity to carry out UV, NMR and ESR spectroscopic studies.

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Authors and Affiliations

  1. Federal State Ufa Institute of Chemistry, Russian Academy of Sciences, pr. Oktyabrya 71, Ufa, 450054, Russia

    N. M. Andriyashina, S. A. Grabovskii & N. N. Kabal’nova

Authors
  1. N. M. Andriyashina
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  2. S. A. Grabovskii
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  3. N. N. Kabal’nova
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Corresponding author

Correspondence to S. A. Grabovskii.

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Conflict of Interest

No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 8, pp. 1164–1168.

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Andriyashina, N.M., Grabovskii, S.A. & Kabal’nova, N.N. Decomposition of Benzoyl Peroxide in the Presence of Ferrocene. Russ J Gen Chem 89, 1560–1563 (2019). https://doi.org/10.1134/S1070363219080036

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  • DOI: https://doi.org/10.1134/S1070363219080036

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