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Preparation and spectral properties of β-bromo-substituted Mn(III) tetraphenylporphyrinates

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Abstract

Interaction of 5,10,15,20-tetraphenylporphyrin, 2-bromo-5,10,15,20-tetraphenylporphyrin, and 2,3,12,13-tetrabromo-5,10,15,20-tetraphenylporphyrin with manganese(II) chloride in dimethylformamide has been studied by means of spectrophotometry. The corresponding chloride acido complexes of manganese(III) has been so prepared and identified. The complexes could be reduced into manganese(II) tetraphenylporphyrinates in the presence of potassium hydroxide in dimethylformamide.

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Authors and Affiliations

  1. Krestov Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153040, Russia

    N. V. Chizhova, S. V. Zvezdina & N. Zh. Mamardashvili

  2. Ivanovo State Chemical-Technological University, Ivanovo, Russia

    Yu. S. Kataleva

Authors
  1. N. V. Chizhova
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  2. S. V. Zvezdina
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  3. Yu. S. Kataleva
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  4. N. Zh. Mamardashvili
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Correspondence to N. V. Chizhova.

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Original Russian Text © N.V. Chizhova, S.V. Zvezdina, Yu.S. Kataleva, N.Zh. Mamardashvili, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 5, pp. 838–841.

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Chizhova, N.V., Zvezdina, S.V., Kataleva, Y.S. et al. Preparation and spectral properties of β-bromo-substituted Mn(III) tetraphenylporphyrinates. Russ J Gen Chem 85, 1132–1135 (2015). https://doi.org/10.1134/S1070363215050217

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  • DOI: https://doi.org/10.1134/S1070363215050217

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