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The reactivity of 1-vinyl-1,2,4-triazole in the radical copolymerization with crotonic aldehyde

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Abstract

Copolymerization of 1-vinyl-1,2,4-triazole with crotonic aldehyde under the conditions of free-radical initiation has been studied. 1-Vinyl-1,2,4-triazole was found to be more reactive than crotonic aldehyde. The composition and structure of copolymers were determined by the elemental analysis, IR and quantitative 13C NMR spectroscopy. New polyfunctional water-soluble copolymers possessing thermostability up to 300°C were obtained.

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Correspondence to A. S. Pozdnyakov.

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Dedicated to the 90th Anniversary of Academician M.G. Voronkov

Original Russian Text © A.S. Pozdnyakov, T.G. Ermakova, L.V. Kanitskaya, N.P. Kuznetsova, S.A. Korzhova, G.F. Prozorova, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 1, pp. 91–94.

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Pozdnyakov, A.S., Ermakova, T.G., Kanitskaya, L.V. et al. The reactivity of 1-vinyl-1,2,4-triazole in the radical copolymerization with crotonic aldehyde. Russ J Gen Chem 82, 87–90 (2012). https://doi.org/10.1134/S1070363212010148

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  • DOI: https://doi.org/10.1134/S1070363212010148

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