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New heterosilocanes, 1,1-difluoroand 1-phenyl-1-fluoro-2,8-dioxa-5-chalcogenosilocanes

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Abstract

The earlier unknown Si-fluorinated 2,8-dioxa-5-chalcogenosilocanes RFSi(OCH2CH2)2Y (R = Ph, F; Y = O, S) were synthesized. According to calculations, there is a weak transannular coordinate interaction Y→Si (Y = O, S), which is much weaker than that in the isostructural quasisilatranes (Y = N). At low temperatures, 1,1-difluoro-2,5,8-trioxasilocane forms a dimer, in which two molecules of the monomer are linked by four fluorine bridges Si-F→Si located in pairs in the two orthogonal planes SiF2Si.

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Correspondence to O. M. Trofimova.

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Original Russian Text © M.G. Voronkov, O.M. Trofimova, E.A. Grebneva, A.I. Albanov, T.N. Aksamentova, N.N. Chipanina, A.S. Soldatenko, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 7, pp. 1110–1116.

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Voronkov, M.G., Trofimova, O.M., Grebneva, E.A. et al. New heterosilocanes, 1,1-difluoroand 1-phenyl-1-fluoro-2,8-dioxa-5-chalcogenosilocanes. Russ J Gen Chem 80, 1276–1282 (2010). https://doi.org/10.1134/S1070363210070108

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  • DOI: https://doi.org/10.1134/S1070363210070108

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