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A five-coordinate complex of copper chloride with 2-amino-5-ethyl-1,3,4-thiadiazole

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Abstract

A complex of Cu(II) chloride with 2-amino-5-ethyl-1,3,4-thiadiazole (AET) was prepared, and its structure was studied by IR spectroscopy and single crystal X-ray diffraction. The complex has the composition CuCl2(AET)4. The coordination sphere of the copper atom includes four molecules of the heterocyclic ligand coordinated via N atoms of thiadiazole rings and one of Cl− anions; the second Cl− anion is in the outer sphere.

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Authors and Affiliations

  1. Ulugbek National University of Uzbekistan, Vuzgorodok, Tashkent, 700174, Uzbekistan

    Sh. A. Kadirova & N. A. Parpiev

  2. St. Petersburg State Technological University of Plant Polymers, St. Petersburg, Russia

    M. M. Ishankhodzhaeva

  3. Tashkent Institute of Irrigation and Melioration, Tashkent, Uzbekistan

    Z. Karimov

  4. Yunusov Institute of Chemistry of Plant Substances, Academy of Sciences of Uzbekistan Republic, Tashkent, Uzbekistan

    A. Tozhiboev & B. Tashkhodzhaev

Authors
  1. Sh. A. Kadirova
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  2. M. M. Ishankhodzhaeva
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  3. N. A. Parpiev
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  4. Z. Karimov
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  5. A. Tozhiboev
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  6. B. Tashkhodzhaev
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Additional information

Original Russian Text © Sh.A. Kadirova, M.M. Ishankhodzhaeva, N.A. Parpiev, Z. Karimov, A. Tozhiboev, B. Tashkhodzhaev, 2007, published in Zhurnal Obshchei Khimii, 2007, Vol. 77, No. 10, pp. 1734–1737.

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Kadirova, S.A., Ishankhodzhaeva, M.M., Parpiev, N.A. et al. A five-coordinate complex of copper chloride with 2-amino-5-ethyl-1,3,4-thiadiazole. Russ J Gen Chem 77, 1799–1801 (2007). https://doi.org/10.1134/S1070363207100210

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  • DOI: https://doi.org/10.1134/S1070363207100210

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