Abstract
The structural parameters of the molecules of sodium hydroxymethane-, 1-hydroxyethane-, 1-hydroxypropane-, aminomethane-, and dimethylaminomethanesulfinates, aminoiminomethanesulfinic acid, and thiourea dioxide were studied by Hartree-Fock-Roothaan and DFT quantum-chemical calculations. The C-S bond length in these molecules varies in the same direction as the constants characterizing their decomposition in aqueous solutions.
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Original Russian Text © Yu.V. Polenov, V.V. Sliznev, S.B. Lapshina, S.A. Koksharov, A.V. Nikolaev, E. V. Egorova, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 7, pp. 1138–1142.
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Polenov, Y.V., Sliznev, V.V., Lapshina, S.B. et al. Structure and kinetic stability of 1-hydroxy-and aminoalkalnesulfinates in aqueous solutions. Russ J Gen Chem 76, 1090–1094 (2006). https://doi.org/10.1134/S1070363206070141
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DOI: https://doi.org/10.1134/S1070363206070141