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Heterometallic Ln(III)–Cd(II) Complexes with Anions of Monocarboxylic Acids: Synthetic Approaches and Analysis of Structures and Photoluminescence Properties

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Abstract

The results of studying heterometallic complexes Ln(III)–Cd(II) with anions of aromatic and aliphatic monocarboxylic acids are generalized. A number of substantial features is observed in complexes Ln(III)–Cd(II), but they are not characteristic of compounds Ln(III)–М(II) with 3d-metal ions (M = Co, Ni, Cu, Zn). A tendency of the cadmium(II) complexes to form coordination polymers at the compositions typical of the molecular 3d-metal complexes is shown. The effect of the substituent in benzoic acid on the structures and photoluminescence properties of the heterometallic Ln(III)–Cd(II) complexes is revealed.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation in terms of state assignment of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119992, Moscow, Russia

    M. A. Shmelev, N. V. Gogoleva, V. K. Ivanov, V. V. Kovalev, G. A. Razgonyaeva, M. A. Kiskin, A. A. Sidorov & I. L. Eremenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    I. L. Eremenko

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  1. M. A. Shmelev
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  2. N. V. Gogoleva
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Translated by E. Yablonskaya

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Shmelev, M.A., Gogoleva, N.V., Ivanov, V.K. et al. Heterometallic Ln(III)–Cd(II) Complexes with Anions of Monocarboxylic Acids: Synthetic Approaches and Analysis of Structures and Photoluminescence Properties. Russ J Coord Chem 48, 539–556 (2022). https://doi.org/10.1134/S1070328422090056

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