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A Concise Synthesis of N-Methyl-2,3-diferrocenyl-4,4-dicyanopyrrolidine through [3 + 2] Cycloaddition of Azomethine Ylides

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Abstract

Microwave-assisted synthesis of N-methyl-2,3-diferrocenyl-4,4-dicyanopyrrolidine has been accomplished in moderate yields via a facile 1,3-dipolar cycloaddition and its crystal structure was determined by single-crystal X-ray diffraction (CCDC no. 1583719). It crystallizes: C27H25Fe2N3, Mr = 503.20, orthorhombic, P212121, a = 10.4873(9), b = 10.5251(10), c = 20.8587(19) Å, V = 2302.4(4) Å3, ρ = 1.452 g cm−3, Z = 4, T = 298(2) K.

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Funding

This work was supported by Natural Science Foundation of of Hebei Science and Technology Department (no. ZD2019095).

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Authors and Affiliations

  1. College of Sciences, Hebei University of Science and Technology, 050018, Shijiazhuang, P.R. China

    Y. M. Zhang, X. H. Liu & P. Liu

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  1. Y. M. Zhang
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  2. X. H. Liu
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  3. P. Liu
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Correspondence to Y. M. Zhang.

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Zhang, Y.M., Liu, X.H. & Liu, P. A Concise Synthesis of N-Methyl-2,3-diferrocenyl-4,4-dicyanopyrrolidine through [3 + 2] Cycloaddition of Azomethine Ylides. Russ J Coord Chem 47, 653–656 (2021). https://doi.org/10.1134/S1070328421090104

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