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The Reaction of Re3Br9 with P(CH2OH)3: Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters

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Abstract

The reaction of Re3Br9 with P(CH2OH)3 (THP) in methanol under inert atmosphere gives a new cluster complex, [Re3(µ2‑Br)3Br3(µ3-P,O,O-P(CH2OH)(CH2O)2)2H] ∙ 0.8H2O · 1.6MeOH (I). With access of air, the reaction produces a different product, [{Re3(µ2-Br)3Br2(OCH2)2PCH2-OP(CH2OH)2}2-{(P(CH2OH)(CH2O)2)}2] (II), in which two triangular clusters are linked by deprotonated THP molecules as bridging ligands. In addition, each cluster is coordinated in a tetradentate fashion by the phosphine-phosphinite ligand, resulting from the oxidative condensation of two THP molecules (CIF files CCDC 1829565 (I) and 1829566 (II)).

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Funding

The work was supported by the Russian Foundation for Basic Research (grant no. 17-03-00663).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Anyushin, P. A. Abramov & M. N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russia

    P. A. Abramov & M. N. Sokolov

  3. Kazan (Volga Region) Federal University, Kazan, Russia

    M. N. Sokolov

Authors
  1. A. V. Anyushin
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  2. P. A. Abramov
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  3. M. N. Sokolov
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Contributions

M.N. Sokolov (Head of the Project) put forward the idea and discussed the results; A.V. Anyushin (principal investigator) conducted experiments. P.A. Abramov performed X-ray diffraction analysis. M.N. Sokolov and A.V. Anyushin co-wrote the paper.

Corresponding author

Correspondence to M. N. Sokolov.

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The authors declare that they have no conflict of interest.

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Translated by Z. Svitanko

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Anyushin, A.V., Abramov, P.A. & Sokolov, M.N. The Reaction of Re3Br9 with P(CH2OH)3: Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters. Russ J Coord Chem 45, 548–554 (2019). https://doi.org/10.1134/S1070328419080013

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  • DOI: https://doi.org/10.1134/S1070328419080013

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