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A 3D europium-organic-framework from phenyl imidazole dicarboxylate showing high sensitivity in detection of nitrobenzene

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Abstract

A Eu-based luminescent MOF, namely, {[Eu(µ3-HPhIDC)(µ2-C2O4)0.5(H2O)] · 2H2O} n (I) (H3PhIDC = 2-phenyl-1H-imidazole-4,5-dicarboxylic acid) has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction techniques (CIF file CCDC no. 1457365). The MOF I indicates characteristic sharp emission bands of Eu3+ ion, which is selectively sensitive to nitrobenzene- based derivatives (nitrobenzene, 2-nitrotoluene, 3-nitrotoluene, 1,3-dinitrobenzene and 2,4-dinitrotoluene). These properties make I a potential fluorescence sensor for these chemicals.

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Authors and Affiliations

  1. Department of Chemical Engineering, Henan Polytechnic Institute, Nanyang Henan, 473009, P.R. China

    Q. Y. Huang

  2. Department of Chemical Engineering, Henan Vocational College of Applied Technology, Zhengzhou Henan, 450042, P.R. China

    Y. Zhao

  3. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou Henan, 450001, P.R. China

    L. Fu & G. Li

Authors
  1. Q. Y. Huang
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  2. Y. Zhao
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  3. L. Fu
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  4. G. Li
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Correspondence to G. Li.

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Huang, Q.Y., Zhao, Y., Fu, L. et al. A 3D europium-organic-framework from phenyl imidazole dicarboxylate showing high sensitivity in detection of nitrobenzene. Russ J Coord Chem 43, 604–611 (2017). https://doi.org/10.1134/S1070328417090032

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  • DOI: https://doi.org/10.1134/S1070328417090032

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