Abstract
Compositions of mixed ligand acetate, propionate, and pivalate complexes of rare earth metals of the cerium and yttrium groups with monoethanolamine are predetermined by the synthesis conditions and the nature of the carboxylate ligand and rare earth metal ion. Solid mixed ligand complexes [Ln(Piv)5(MEAH)][MEAH] and [Ln(Piv)3(MEA)], homoligand complexes [Ln(Piv)3] (HPiv is 2,2-dimethylpropionic (pivalic) acid), and gel-like hydroxo complexes [Ln(Carb)3–x–y (NO3) x -(OH) y (MEA) w (H2O) z ] (HCarb is acetic (HAc) or propionic (HProp) acid) are isolated using original synthesis procedures involving ion pairs [MEAH]+[Carb]– (MEA is monoethanolamine). The compounds are studied by IR spectroscopy, 1H NMR spectroscopy, elemental and thermal analyses, and mass spectrometry. Specific features for the complex formation of rare earth metal pivalates with MEA are additionally studied using quantum-chemical simulation.
Similar content being viewed by others
References
Martin, L.W., Chu, Y.-H., and Ramesh, R., Mater. Sci. Eng., R., 2010, vol. 68, p. 165.
Chemical Solution Deposition of Functional Oxide Thin Films, Schneller, T., Waser, R., Kosec, M., and Payne, D., Eds., Dordrecht: Springer, 2013.
Shaplygin, I.S., Komarov, V.P., and Lazarev, V.B., J. Therm. Anal., 1979, vol. 15, p. 215.
Mayer, I. and Kassierer, F., J. Inorg. Nucl. Chem., 1966, vol. 28, p. 2430.
Patil, K.C., Chandrashekhar, G.V., George, M.V., et al., Can. J. Chem., 1968, vol. 46, p. 257.
Arii, T., Kishi, A., Ogawa, M., et al., Anal. Sci., 2001, vol. 17, p. 875.
Gmelin Handbook of Inorganic Chemistry, Berlin, 1984, Syst No. 39, vol. D5.
Junk, P.C., Kepert, C.J., Min, W., et al., Aust. J. Chem., 1999, vol. 52, p. 437.
Ouchi, A., Coord. Chem. Rev., 1988, vol. 92, p. 29.
Ciontea, L., Nasui, M., Petrisor, T.Jr., et al., Mater. Res. Bull., 2010, vol. 45, p. 1203.
Martynova, I.A., Tsymbarenko, D.M., and Kuz’mina, N.P., Russ. J. Coord. Chem., 2014, vol. 40, no. 8, p. 565.
Khudyakov, M.Yu., Kuz’mina, N.P., Pisarevskii, A.P., et al., Russ. J. Coord. Chem., 2002, vol. 28, no. 7, p. 521.
Dobrokhotova, Zh.V., Fomina, I.G., Aleksandrov, G.G., et al., Russ. J. Inorg. Chem., 2009, vol. 54, no. 5, p. 668.
Kiseleva, E.A., Troyanov, S.I., and Korenev, Yu.M., Russ. J. Coord. Chem., 2006, vol. 32, no. 1, p. 57.
Porai-Koshits, M.A., Itogi Nauki Tekh., Ser.: Kristallokhim., Moscow: VINITI, 1981.
Gharia, K.S., Singh, M., Mathur, S., et al., Synt. React. Inorg. Met.-Org. Chem., 1980, vol. 10, p. 403.
Tudor, V., Marin, G., Lloret, F., et al., Inorg. Chim. Acta, 2008, vol. 361, p. 3446.
Kufelnicki, A., Tomyn, S.V., Nedelkov, R.V., et al., Inorg. Chim. Acta, 2010, vol. 363, p. 2996.
Yilmaz, V.T., Andac, O., Karadag, A., et al., J. Mol. Struct., 2002, vol. 641, p. 119.
Kuz’mina, N.P., Ibragimov, S.A., Makarevich, A.M., et al., Chem. Mater., 2010, vol. 22, p. 5803.
Martynova, I.A., Kardashev, S.V., and Kuz’mina, N.P., Vestn. Mosk. Univ., Ser. 2: Khim., 2012, vol. 53, no. 1, p. 24.
Kuz’mina, N.P., Martynova, I.A., Tsymbarenko, D.M., et al., Inorg. Chem. Commun., 2011, vol. 14, p. 180.
Pinkert, A., Marsh, K.N., and Pang, S., Ind. Eng. Chem. Res., 2010, vol. 49, p. 11809.
Temin, S.C., Org. Chem., 1956, vol. 21, p. 250.
Kuzmina, N.P., Martynenko, L.I., Zoan T.A., et al., Neorg. Khim., 1994, vol. 39, no. 4, p. 538.
Abbas, G., Lan, Y., Kostakis, G., et al., Inorg. Chim. Acta, 2008, vol. 361, p. 3494.
Reutov, O.A., Kurts, A.L., and Butin, K.P., Organicheskaya khimiya (Organic Chemistry), Moscow: Binom. Laboratoriya znanii, 2004, part 3, p. 421.
Gutmann, V., The Donor Acceptor Approach to Molecular Interactions, New York: Plenum, 1978.
Burger, K., Solvation, Ionic and Complex Formation Reactions in Non-aqueous Solvents, Budapest: Akadémiai Kiadó, 1983, p. 268.
Kharchenko, A.V., Makarevich, A.M., Lysenko, K.A., et al., Russ. J. Coord. Chem., 2010, vol. 36, no. 11, p. 804.
Fomina, I., Dobrokhotova, Zh., and Aleksandrov, G., J. Solid State Chem., 2012, vol. 185, p. 49.
Sidorov, L.N., Korobov, M.V., and Zhuravleva, L.V., Mass-spektral’nye termodinamicheskie issledovaniya (Mass-Spectral Thermodynamic Investigtions), Moscow: Mosk. Univ., 1985.
Malkerova, I.P., Alikhanyan, A.S., Fomina, I.G., et al., Russ. J. Inorg. Chem., 2009, vol. 54, no. 5, p. 734.
Malkerova, I.P., Alikhanyan, A.S., Fomina, I.G., et al., Russ. J. Inorg. Chem., 2010, vol. 55, no. 1, p. 53.
Zoan, T.A., Kuzmina, N.P., Frolovskaya, S.N., et al., J. Alloys Comp., 1995, vol. 225, p. 396.
Santos, L.S., J. Chem. Thermodyn., 1997, vol. 29, p. 661.
Sicre, J.E., J. Am. Chem. Soc., 1969, vol. 91, no. 13, p. 3476.
Martynova, I.A., Tsymbarenko, D.M., Kamenev, A.A., et al., Izv. Akad. Nauk, Ser. Khim., 2013, vol. 62, no. 6, p. 1454.
Sheldrick, G.M., SHELXTL. Version 5.10. Structure Determination Software Suite, Madison: Bruker AXS, 1998.
Granovsky, A.A., Firefly version 8, http://classic. chem.msu.su/gran/firefly/index.htm
Dolg, M., Stoll, H., Savin, A., et al., Theor. Chim. Acta, 1989, vol. 75, p. 173.
Dolg, M., Stoll, H., and Preuss, H., Theor. Chim. Acta, 1993, vol. 85, p. 441.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © D.M. Tsymbarenko, I.A. Martynova, I.P. Malkerova, A.S. Alikhanyan, N.P. Kuzmina, 2016, published in Koordinatsionnaya Khimiya, 2016, Vol. 42, No. 10, pp. 624–639.
Rights and permissions
About this article
Cite this article
Tsymbarenko, D.M., Martynova, I.A., Malkerova, I.P. et al. Mixed ligand acetate, propionate, and pivalate complexes of rare earth metals with monoethanolamine: A new approach to the synthesis, composition, structure, and use for the preparation of oxide materials. Russ J Coord Chem 42, 662–678 (2016). https://doi.org/10.1134/S1070328416100043
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328416100043