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Synthesis and crystal structure of a new nickel(II) coordination polymer based on Schiff base

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Abstract

A new Schiff base coordination polymer, [Ni(C18H16N3O2)2 · 2CH3OH] n (C18H16N3O2, 2-acetylpyridine-L-tryptophan), was synthesized and characterized by IR, UV, and X-ray diffraction singlecrystal analysis. The crystal crystallizes in the tetragonal crystal system, space group P43212 with cell parameters a = 11.8912(11), c = 28.822(3) Å, V = 4075.5(6) Å3, Z = 4, F(000) = 1544, S = 1.187, ρcalcd = 1.199 g cm−3, μ = 0.525 mm−1, the final R 1 = 0.0515 and wR 2 = 0.1513 for 3602 observed reflections (I > 2σ(I)). The Ni(II) atom is six-coordinated by two nitrogen atoms from C=N, two nitrogen atoms from pyridine rings and two carboxylic oxygen atoms in different ligands, forming a distorted octahedron geometry. Each ligand serves as a bridging ligand to link Ni2+ ions through carboxylic oxygen atoms, leading to a two-dimensional coordination polymer.

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Authors and Affiliations

  1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100, P.R. China

    N. Zhang, Y. H. Fan, C. F. Bi, J. Zuo & Q. Wang

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  1. N. Zhang
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  2. Y. H. Fan
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  3. C. F. Bi
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  4. J. Zuo
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  5. Q. Wang
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Correspondence to Y. H. Fan.

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Zhang, N., Fan, Y.H., Bi, C.F. et al. Synthesis and crystal structure of a new nickel(II) coordination polymer based on Schiff base. Russ J Coord Chem 38, 349–352 (2012). https://doi.org/10.1134/S1070328412050119

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  • DOI: https://doi.org/10.1134/S1070328412050119

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