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Transition metal complexes with 2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone

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Abstract

2-(N-Tosylamino)benzaldehyde 1-phthalazinylhydrazone (H2L) and its complexes with Cu(II), Ni(II), and Mn(II) were obtained. The acid-basic properties of the hydrazone were studied using potentiometry and spectrophotometry. The experimental data were compared with the results of quantum-chemical DFT calculations. The structure of the binuclear complex [Cu2L2] was determined using X-ray diffraction. The broken symmetry approach was used to calculate the exchange coupling constant of the copper ions.

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Authors and Affiliations

  1. Southern Federal University, Rostov-on-Don, Russia

    L. D. Popov, I. N. Shcherbakov, Yu. P. Tupolova, A. S. Burlov, V. V. Lukov & V. A. Kogan

  2. Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia

    S. I. Levchenkov

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. G. Aleksandrov

Authors
  1. L. D. Popov
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  2. I. N. Shcherbakov
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  3. S. I. Levchenkov
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  4. Yu. P. Tupolova
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  5. A. S. Burlov
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  6. G. G. Aleksandrov
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  7. V. V. Lukov
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  8. V. A. Kogan
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Correspondence to S. I. Levchenkov.

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Original Russian Text © L.D. Popov, I.N. Shcherbakov, S.I. Levchenkov, Yu.P. Tupolova, A.S. Burlov, G.G. Aleksandrov, V.V. Lukov, V.A. Kogan, 2011, published in Koordinatsionnaya Khimiya, 2011, Vol. 37, No. 7, pp. 483–491.

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Popov, L.D., Shcherbakov, I.N., Levchenkov, S.I. et al. Transition metal complexes with 2-(N-tosylamino)benzaldehyde 1-phthalazinylhydrazone. Russ J Coord Chem 37, 483–491 (2011). https://doi.org/10.1134/S1070328411060078

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