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New complex of zinc(II) with schiff base derived from furaldehyde and diethylenetriamine: Synthesis and crystal structure

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Abstract

A new zinc(II) complex, ZnLCl2 (L = N,N′-bis(furaldehyde)diethylenetriamine), was synthesized and characterized by X-ray crystallography analysis. The crystal belongs to the triclinic crystal system, space group \( P\bar 1 \), with cell parameters a = 7.365(5), b = 13.591(9), c = 17.627(11) Å, α = 94.386(12)°, β = 93.643(11)°, γ = 91.535(10)°, Z = 4, R 1 = 0.0478, and wR 2 = 0.0618. The coordination geometry around Zn(II) is a distorted tetrahedron containing one bidenate N,N′-bis(furaldehyde)diethylenetriamine ligand and two Cl− ions.

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Authors and Affiliations

  1. Department of Chemical Engineering, College of Environment and Engineering, Chang’an University, Xi’an, 710054, P.R. China

    W. Wang

  2. Department of Chemistry, Northwest University, Shaanxi Province Key Laboratory of Physicoinorganic Chemistry, Xi’an, 710069, P.R. China

    W. Wang, F. X. Zhang, J. Li & W. B. Hu

Authors
  1. W. Wang
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  2. F. X. Zhang
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  3. J. Li
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  4. W. B. Hu
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Correspondence to W. Wang.

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Wang, W., Zhang, F.X., Li, J. et al. New complex of zinc(II) with schiff base derived from furaldehyde and diethylenetriamine: Synthesis and crystal structure. Russ J Coord Chem 36, 33–36 (2010). https://doi.org/10.1134/S1070328410010057

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  • DOI: https://doi.org/10.1134/S1070328410010057

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