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Synthesis, crystal structure, and photoluminescence of zinc complex [Zn(Qina)2(DMSO)2] · 2DMSO

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Abstract

A novel complex [Zn(Qina)2(DMSO)2] · 2DMSO (I) (Qina = quinaldic acid, DMSO = dimethyl sulfoxide) has been synthesized and characterized by X-ray diffraction, elementary analysis, and IR spectrum. The unit cell parameters for complex I: a = 8.2884(11), b = 22.015(3), c = 9.0685(12) Å, β = 100.61(0)°, V = 1626.41(40) Å3, Z = 2, space group, P21/n. In the complex I, the Zn(II) atom was six-coordinated to form a distorted octahedral geometry by two Qina ligands and two dimethyl sulfoxide molecules. The crystal structure is stabilized by hydrogen bonds, C - H... π, π-π stacking interaction between adjacent complexes. The binding of the complex I with calf thymus DNA has been investigated by fluorescence spectroscopic studies. The result suggested that the complex intercalates into DNA base pairs.

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Authors and Affiliations

  1. Coordination Chemistry Laboratory, Shenyang Institute of Chemical Technology, Shenyang, Liaoning, 110142, P.R. China

    W. Z. Zhang, Ma Shuang, M. C. Zhu, Liu Lei & E. J. Gao

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  1. W. Z. Zhang
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  2. Ma Shuang
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  3. M. C. Zhu
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  4. Liu Lei
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  5. E. J. Gao
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Correspondence to E. J. Gao.

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Zhang, W.Z., Shuang, M., Zhu, M.C. et al. Synthesis, crystal structure, and photoluminescence of zinc complex [Zn(Qina)2(DMSO)2] · 2DMSO. Russ J Coord Chem 35, 874–878 (2009). https://doi.org/10.1134/S1070328409120021

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  • DOI: https://doi.org/10.1134/S1070328409120021

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