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New crystalline modification of μ-oxo-bis(bromotriphenylantimony)

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Abstract

The triclinic crystalline modification of μ-oxo-bis(bromotriphenylantimony) has been synthesized by the reaction of triphenylantimmony dibromide with water in benzene. The Sb atoms have distorted trigonal bipyramidal coordination with the bromine atoms and bridging oxygen atoms in the axial positions. The distances are Sb-C 2.104(2)-2.123(2), Sb(1)-Br(1) 2.7492(2), Sb(2)-Br(2) 2.7235(2), Sb(1)-O 1.986(1), and Sb(2)-O 1.987(1) Å, and the Sb(1)OSb(2) angle is 138.19(6)°.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, A. P. Pakusina, I. V. Egorova & O. K. Sharutina

  2. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    M. A. Pushilin

Authors
  1. V. V. Sharutin
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  2. A. P. Pakusina
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  3. I. V. Egorova
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  4. O. K. Sharutina
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  5. M. A. Pushilin
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, A.P. Pakusina, I.V. Egorova, O.K. Sharutina, M.A. Pushilin, 2008, published in Koordinatsionnaya Khimiya, 2008, Vol. 34, No. 3, pp. 181–184.

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Sharutin, V.V., Pakusina, A.P., Egorova, I.V. et al. New crystalline modification of μ-oxo-bis(bromotriphenylantimony). Russ J Coord Chem 34, 175–178 (2008). https://doi.org/10.1134/S1070328408030044

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  • DOI: https://doi.org/10.1134/S1070328408030044

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