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Dynamics of the order parameter and the potential of the hydrogen bond in a ferroelectric DKDP crystal

  • Order, Disorder, and Phase Transition in Condensed System
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Abstract

Within a pseudospin model of a KD2PO4 crystal, the relaxation time of the average pseudospin (the order parameter) in the mean-field approximation depends on the activation energy of the jump of a deuteron between the minima of the hydrogen bond potential, the average equilibrium value of the pseudospin, and the dielectric susceptibility. Calculating the average equilibrium spin and the susceptibility within the four-particle cluster approximation and fitting the data for the width of the central peak from a Raman scattering experiment, we numerically estimate the activation energy. For the same values of the parameters of the cluster method, the calculated inverse relaxation time is in good agreement with the data of ultrasonic measurements.

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Authors and Affiliations

  1. Institute of Automatics and Electrometry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Koptyuga 1, Novosibirsk, 630090, Russia

    V. A. Abalmassov, A. M. Pugachev & N. V. Surovtsev

Authors
  1. V. A. Abalmassov
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  2. A. M. Pugachev
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  3. N. V. Surovtsev
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Correspondence to V. A. Abalmassov.

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Original Russian Text © V.A. Abalmassov, A.M. Pugachev, N.V. Surovtsev, 2013, published in Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2013, Vol. 143, No. 2, pp. 322–328.

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Abalmassov, V.A., Pugachev, A.M. & Surovtsev, N.V. Dynamics of the order parameter and the potential of the hydrogen bond in a ferroelectric DKDP crystal. J. Exp. Theor. Phys. 116, 280–285 (2013). https://doi.org/10.1134/S1063776113020076

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  • DOI: https://doi.org/10.1134/S1063776113020076

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