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A New Coordination Polymer Based on Citric Acid Containing 1D [Ag]∞ Chain with Strong Ag–Ag Bonding Interaction

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Abstract

A new polynuclear silver complex Ag6(W2O5)(Cid)2 based on citric acid is obtained by hydrothermal method and studied by single crystal X-ray diffraction compound The compound crystallizes in triclinic space group P\(\bar {1}\), Z = 1. The structure solution is complicated by two component non-merohedral twinning. The structure feature is a 3D framework containing 1D infinite [Ag]∞ chains. Ag atoms are connected by metal–metal bonding interaction with the Ag–Ag distances of 2.849(3)–3.218(2) Å.

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ACKNOWLEDGMENTS

This work was supported by National Science Foundation of China (Grant no. 21201056), Science and Technology Research Project of Henan Province (no. 172102310678), and the Fundamental Research Funds for the Universities of Henan Province (NSFRF170301).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Henan Polytechnic University, 454000, Jiaozuo, Henan, China

    D. Zhao, Z. Ma & Q. Zong

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  1. D. Zhao
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  2. Z. Ma
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  3. Q. Zong
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Correspondence to D. Zhao.

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Zhao, D., Ma, Z. & Zong, Q. A New Coordination Polymer Based on Citric Acid Containing 1D [Ag]∞ Chain with Strong Ag–Ag Bonding Interaction. Crystallogr. Rep. 64, 1019–1022 (2019). https://doi.org/10.1134/S1063774519070290

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  • DOI: https://doi.org/10.1134/S1063774519070290

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