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Simultaneous Determination of Copper(II) and Cobalt(II) Ions, Copper(II) and Manganese(II) Ions in Drinking Water Using Indicator Test Tubes Based on Carboxylic Cation-Exchangers

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Abstract

We investigated a possibility of determining two metal ions (Cu2+ and Co2+, Cu2+ and Mn2+) in a single water sample using an indicator test tube filled with a carboxylic cation exchanger of a macrocellular (KB-2E-10, KB-2E-16) or a macroporous (Tokem-250) structure. Under dynamic conditions, the separation of the chromatographic zones of colored Cu2+ and Co2+ ions was achieved in the presence of water macro components, that is, Ca2+ and Mg2+ ions. An analytical reagent, formaldoxime, was used to determine colorless Mn2+ ions. The performance characteristics of the developed procedures are determined. The lowest limit of detection for ions was obtained using a KB-2E-16 cation exchanger; it is 0.016 mg/L for Cu2+, 0.045 mg/L for Co2+, and 0.003 mg/L for Mn2+. The proposed procedures were used to analyze real samples for the concentration of Co2+ and Cu2+ or Mn2+ and Cu2+ on their simultaneous presence. The accuracy of the results was evaluated by the standard addition method.

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  1. Department of Chemistry, National Research Tomsk State University, 634050, Tomsk, Russia

    V. V. Zharkova & L. A. Bobkova

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  1. V. V. Zharkova
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  2. L. A. Bobkova
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Correspondence to V. V. Zharkova.

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Translated by O. Zhukova

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Zharkova, V.V., Bobkova, L.A. Simultaneous Determination of Copper(II) and Cobalt(II) Ions, Copper(II) and Manganese(II) Ions in Drinking Water Using Indicator Test Tubes Based on Carboxylic Cation-Exchangers. J Anal Chem 74, 672–678 (2019). https://doi.org/10.1134/S1061934819050125

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