Abstract
Direct headspace gas chromatographic analysis with flame ionization and mass spectrometric detection was used to identify and quantify volatile organic compounds (VOCs) in the headspace of the medicinal plant material of Common Tansy (Tanacetum vulgare L.) and preparations of its oil and tablet dry extract. All the main components of the headspace of medicinal plant raw material of Tansy are present in the headspace of phytopreparations. The retention indices of VOCs \(\left( {I_{i}^{T}} \right)\) were determined for the linear programmed temperature of a column with a 5% diphenyl–95% dimethylpolysiloxane stationary phase and the relative peak areas (Arl,i) in the chromatogram are determined. It is shown that the specific chromatographic profiles of VOCs, which represent the set of values of \(I_{i}^{T}\) and Arl,i, for Tansy samples from different regions of Russia are similar.
Similar content being viewed by others
REFERENCES
Zenkevich, I.G., Bagirova, V.L., Sokol’skaya, T.A., and Nechaeva, E.B., Farmatsiya, 2002, no. 2, p. 45.
Okoh, O., Sadimenko, A.P., Asekun, O.T., and Afolayan, A.J., Afr. J. Biotechnol., 2008, no. 7(10), p. 1500.
Kaskoniene, V., Kaskonas, P., and Maruska, M., Chromatographia, 2011, no. 73, p. 163.
Sharopov, F.S., Gulmurodov, I.S., and Setzer, W.N., J. Chem. Pharm. Res., 2010, vol. 2, no. 6, p. 284.
Kuzmenko A.N., Izuchenie komponentnogo sostava rastitel’nogo lekarstvennogo sbora, Moscow Univ. Chem. Bull. (Engl. Transl.), 2009, vol. 50, no. 3, p. 168.
Kuzmenko, A.N., Reshetnyak, V.Yu., Popkov, V.A., Rashkova, E.B., and Pirogov, A.V., Moscow Univ. Chem. Bull. (Engl. Transl.), 2011, vol. 66, no. 5, p. 326.
Razzhivin, R.V., Reshetnyak, V.Yu., Kuz’menko, A.N., Nesterova, O.V., and Popkov, V.A., Moscow Univ. Chem. Bull. (Engl. Transl.), 2009, vol. 64, no. 1, p. 55.
Kuz’menko, A.N., Doctoral (Chem.) Dissertation, Moscow: Sechenov Univ., 2013.
Zolotov, Yu.A., Zavod. Lab., Diagn. Mater., 2012, vol. 78, no. 9, p. 5.
Muresun, M.L., Acta Univ. Cibiniensis, Ser. E: Food Technol., 2015, vol. 19, no. 2, p. 75.
Mockute, D. and Judzentiene, A., Chemija, 2003, vol. 14, no. 2, p. 103.
Rohloff, J., Mordal, R., and Dragland, S., J. Agric. Food Chem., 2004, no. 52, p. 1742.
Collin, J., Deslauriers, H., Pageau, N., and Gagnon, M., J. Essent. Oil Res., 1993, no. 5, p. 629.
Acha de la Cruz, O., Guerrero, J., Podea, R., and Batiu, I., Chem. Bull. “Politeh.” Univ. Timisoara, 2008, vol. 53, nos. 1–2, p. 10.
Pehu, E. and Simon, J.E., Biochem. Syst. Ecol., 2008, no. 29, p. 267.
Muresun, M.L., Oniga, I., Georgescu, C., Paltinean, R., Gligor, F., Tudor, M., and Opren, R., Atmos. Meas. Tech., 2014, vol. 2, no. 4, p. 300.
Pavlova, L.V., Cand. Sci. (Chem.) Dissertation, Samara: Samara State Agric. Univ., 2015.
Revel’skii, I.A. and Glazkov, I.N., Sverkhkrit. Flyuidy: Teor. Prakt., 2008, vol. 3, no. 2, p. 70.
Yashin, Ya.I., Yashin, E.Ya., and Yashin, A.Ya., Gazovaya khromatografiya (Gas Chromatography), Moscow: TransLit, 2009.
Vittenberg, A.G. and Ioffe, B.V., Gazovaya ekstraktsiya v khromatograficheskom analize (Gas Extraction in Chromatographic Analysis), Leningrad: Khimiya, 1982.
Hachenberg, H. and Schmidt, A., Gas Chromatographic Headspace Analysis, London: Heyden, 1976.
Kolb, B. and Leslie, S., Static Headspace–Gas chromatography: Theory and Practice, New York: Wiley, 1997.
Chialva, F., Gabri, G., Liddle, P.A.P., and Ulian, F., J. High Resolut. Chromatogr. Commun., 1982, no. 5, p. 182.
Onuchak, L.A., Arutyunov, Yu.I., Nikitchenko, N.V., Platonov, I.A., and Kurkin, V.A., J. Anal. Chem., 2012, vol. 67, no. 6, p. 560.
Onuchak, L.A., Arutyunov, Yu.I., Maskaeva, E.A., and Ermakova, N.V., Vestn. Samar. Gos. Univ., Estestvennonauchn. Ser., 2014, no. 10(121), p. 153.
Ermakova, N.V., Arutyunov, Yu.I., and Onuchak, L.A., Sorbtsionnye Khromatogr. Protsessy, 2016, vol. 16, no. 1, p. 17.
Kurkin, V.A., Farmakognoziya: Uchebnik dlya studentov farmatsevticheskikh vuzov (Pharmacognosy: Textbook for Students of Pharmaceutical Universities), Samara: Ofort, 2004. 1180 s.
Mil’shina, L.A., Pervyshina, G.G., Efremov, A.A., and Kirienko, N.N., Vestn. Krasnoyarsk. Gos. Agrarn. Univ., 2012, no. 7, p. 75.
Shelepova, O.V., Voronkova, T.V., Kondrat’eva, V.V., Olekhnovich, L.S., and Bidyukova, G.F., Nauch. Vedomosti Belorus. Gos. Univ., Estestv. Nauki, 2014, vol. 29, no. 23(194), p 129.
Tkachev, A.V., Issledovanie letuchikh veshchestv rastenii (Research of Volatile Substances of Plants), Novosibirsk: Ofset, 2008.
Dool, H. and Kratz, P.D., J. Chromatogr. A, 1963, vol. 11, no. 4, p. 463.
Ettre, L.S., Pure Appl. Chem., 1993, vol. 65, no. 4, p. 819.
Doerffel, K., Statistik in der analytischen Chemie (Statistics in Analytical Chemistry), Leipzig: Grundstoffindustrie, 1990, 5 ed.
NIST Database. http://webbook.nist.gov/chemistry. Accessed August, 2017.
ACKNOWLEDGMENTS
The authors are grateful to colleagues from the Department of Pharmacognosy with Botany and the Basics of Phytotherapy of the Samara State Medical University for providing objects of research.
This work was supported within the framework of the state task of the Ministry of Education and Science of the Russian Federation, project no. 4.5883. 2017/8.9.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Zhukova
Rights and permissions
About this article
Cite this article
Onuchak, L.A., Pariichuk, N.V., Arutyunov, Y.I. et al. Headspace Gas Chromatographic Analysis of Volatile Components of Common Tansy (Tanacetum vulgare L.) and Its Preparations. J Anal Chem 73, 1003–1013 (2018). https://doi.org/10.1134/S1061934818100076
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934818100076