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Study of mixed micellar aqueous solutions of sodium dodecyl sulfate and amino acids

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Abstract

Thermodynamic properties of sodium dodecyl sulfate (SDS) in micellar aqueous solutions of L-serine and L-threonine were determined by fluorescence spectroscopy and dynamic light scattering techniques. The values of Gibbs free energy, enthalpy and entropy of the process of micelle formation were calculated using the critical micelle concentration and degree of dissociation. Changes in critical micelle concentration of SDS with the addition of amino acids were examined by both conductivity and pyrene I 1/I 3 ratio methods at different temperatures. The pyrene fluorescence spectra were used to study the change of micropolarity produced by the interaction of SDS with amino acids. The aggregation behavior of SDS was explained in terms of structural changes in mixed solutions. The data on dynamic light scattering suggest that size of SDS micelles was influenced by the presence of amino acids.

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References

  1. Rosen, M.J., Surfactants and Interfacial Phenomena, New York: John Wiley, 1978.

    Google Scholar 

  2. Moroi, Y., Micelles: Theoretical and Applied Aspects, New York: Springer, 1992.

    Google Scholar 

  3. Jones, M.J. and Chapman, D., Micelles, Monolayers and Biomembranes, New York: Wiley-LISS, 1995.

    Google Scholar 

  4. Tanford, C., The Hydrophobic Effect: Formation of Micelles and Biological Membranes, New York: Wiley-Interscience, 1973.

    Google Scholar 

  5. Nagarajan, R., and Ruckenstein, E., J. Colloid Interface Sci., 1979, vol. 71, p. 580.

    Article  CAS  Google Scholar 

  6. Holmberg, K., Johnsson, B., Kronberg, B., and Lindman, B., Surfactants and Polymers in Aqueous Solution, 2nd ed., Chichester: John Wiley, 2003.

    Google Scholar 

  7. Shah, D.O., Micelles, Microemulsions and Monolayers, Boca Raton: CRC Press, 1998.

    Google Scholar 

  8. Pramauro, E. and Pelizzetti, E., Surfactants in Analytical Chemistry: Applications of Organized Amphiphilic Media, Vol. XXXI, Elsevier Science, 1996.

  9. Fendler, J.H., Membrane Mimetic Chemistry: Characterizations and Applications of Micelles, Microemulsions, Monolayers, Bilayers, Vesicles and Host-Guest Systems, New York: John Wiley, 1983.

    Google Scholar 

  10. Paul, B.C., Islam, S.S., and Ismail, K., J. Phys. Chem. B, 1998, vol. 102, p. 7807.

    Article  CAS  Google Scholar 

  11. Dutkiewicz, E., and Jakubowska, A., Colloid Polym. Sci., 2002, vol. 280, p. 1009.

    Article  CAS  Google Scholar 

  12. Bales, B.L., Messina, L., Vidal, A., Peric, M., and Nascimento, O.R., J. Phys. Chem. B, 1998, vol. 102, p. 10347.

    Article  CAS  Google Scholar 

  13. Ranganathan, R., Peric, M., and Bales, B.L., J. Phys. Chem. B, 1998, vol. 102, p. 8436.

    Article  CAS  Google Scholar 

  14. Srinivasan, V. and Blankschtein, D., Langmuir, 2003, vol. 19, p. 9946.

    Article  CAS  Google Scholar 

  15. Neves, A.C.S., Valente, A.J.M., Burrows, H.D., Ribeiro, A.C.F., and Lobo, V.M.M., J. Colloid Interface Sci., 2007, vol. 306, p.166.

    Article  CAS  Google Scholar 

  16. Nordstierna, L., Furo, I., and Stilbs, P., J. Am. Chem. Soc., 2006, vol. 128, p. 6704.

    Article  CAS  Google Scholar 

  17. Schmehl, R.H., Whitesell, L.G., and Whitten, D.G., J. Am. Chem. Soc., 1981, vol. 103, p. 3761.

    Article  CAS  Google Scholar 

  18. Lehninger, A.L., Nelson, D.L., and Cox, M.M., Principles of Biochemistry, Worth Publishers, 1993.

    Google Scholar 

  19. Ali, A., Tariq, M., Patel, R., and Ittoo, F.A., Colloid Polym. Sci., 2008, vol. 286, p. 183.

    Article  CAS  Google Scholar 

  20. Mattice, W.L., Riser, J.M., and Clark, D.S., Biochemistry, 1976, vol. 15, p. 4264.

    Article  CAS  Google Scholar 

  21. Chakraborty, T., Chakraborty, I., Moulik, S.P., and Ghosh, S., J. Phys. Chem. B, 2007, vol. 111, p. 2736.

    Article  CAS  Google Scholar 

  22. Ghosh, S. and Banerjee, A., Biomacromolecules, 2002, vol. 3, p. 9.

    Article  CAS  Google Scholar 

  23. Ghosh, S., Colloids Surf. A, 2005, vol. 264, p. 6.

    Article  CAS  Google Scholar 

  24. Interactions of Surfactants with Polymers and Proteins, Ed. by Ananthapadmanabhan, K.P., Goddard, E.D., and Ananthapadmanabhan, K.P., London: CRC Press, 1993, Chapter 8.

    Google Scholar 

  25. Tanford, C., The Hydrophobic Effect: Formation of Micelles and Biological Membranes, Second ed., New York: Wiley-Interscience, 1980.

    Google Scholar 

  26. Ghosh, S., Colloids Surf. B, 2008, vol. 66, p. 178.

    Article  CAS  Google Scholar 

  27. Malliaris, A., J. Phys. Chem., 1987, vol. 91, p. 6511.

    Article  CAS  Google Scholar 

  28. Burke, S.E., Andrecyk, S.L., and Palepu, R., Colloid Polym. Sci., 2001, vol. 279, p. 131.

    Article  CAS  Google Scholar 

  29. Chauhan, M.S., Kumar, G., Kumar, A., and Chauhan, S., Colloids Surf. A, 2000, vol. 166, p. 51.

    Article  CAS  Google Scholar 

  30. Loginova, L.P., Yakovleva, E.Yu., Galat, M.N., and Boichenko, A.P., J. Mol. Liq., 2009, vol. 145, p. 177.

    Article  CAS  Google Scholar 

  31. Mehta, S.K., Chaudhary, S., Bhasin, K.K., Kumar, R., and Aratono, M., Colloids Surf. A, 2007, vol. 304, p. 88.

    Article  CAS  Google Scholar 

  32. Chauhan, M.S., Kumari, N., Pathania, S., Sharma, K., and Kumar, G., Colloids Surf. A, 2007, vol. 293, p. 157.

    Article  CAS  Google Scholar 

  33. Sharma, V.K., Yadav, O.P., and Singh, J., Colloids Surf. A, 1996, vol. 110, p. 23.

    Article  CAS  Google Scholar 

  34. Bakshi, M.S., Bull. Chem. Soc. Jpn., 1996, vol. 69, p. 2723.

    Article  CAS  Google Scholar 

  35. Lisi, R.D. and Milioto, S., Chem. Soc. Rev., 1994, vol. 23, p. 67.

    Article  Google Scholar 

  36. Bakshi, M.S. and Kohli, P., Indian J. Chem., 1997, vol. 36A, p. 1075.

    CAS  Google Scholar 

  37. Ali, A. and Ansari, N.H., J. Surf. Deterg., 2010, vol. 13, p. 441.

    Article  CAS  Google Scholar 

  38. Deep, S. and Ahluwalia, J.C., Phys. Chem. Chem. Phys., 2001, vol. 3, p. 4583.

    Article  CAS  Google Scholar 

  39. Moroi, Y., and Matsuoka, K., Bull. Chem. Soc. Jpn., 1994, vol. 67, p. 2057.

    Article  CAS  Google Scholar 

  40. Behera, K. and Pandey, S., J. Phys. Chem. B, 2007, vol. 111, p. 13307.

    Article  CAS  Google Scholar 

  41. Behera, K., Om, H., and Pandey, S., J. Phys. Chem. B, 2009, vol. 113, p. 786.

    Article  CAS  Google Scholar 

  42. Fujiwara, M., Okano, T., Nakashima, T.H., Nakamura, A.A., and Sagihara, G., Colloid Polym. Sci., 1997, vol. 275, p. 474.

    Article  CAS  Google Scholar 

  43. Moulik, S.P., Haque, M.E., Jana, P.K., and Das, A.R., J. Phys. Chem., 1996, vol. 100, p. 701.

    Article  CAS  Google Scholar 

  44. Perez, A.G., Castillo, J.L.D., Czapkiewiez, J., and Rodriguez, J.R., Colloids Surf., 2004, vol. 232, p. 183.

    Article  Google Scholar 

  45. Evans, H.C., J. Chem. Soc., 1956, vol. 117, p. 579.

    Article  Google Scholar 

  46. Moore, S.E., Mohareb, M., Moore, S.A., and Palepu, R.M., J. Colloid Interface Sci., 2006, vol. 304, p. 491.

    Article  CAS  Google Scholar 

  47. Shanks, P.C. and Franses, E.I., J. Phys. Chem., 1992, vol. 96, p. 1794.

    Article  CAS  Google Scholar 

  48. Vanyur, R., Biczok, L., and Miskolczy, Z., Colloids Surf. A, 2007, vol. 299, p. 256.

    Article  CAS  Google Scholar 

  49. Bales, B.L., J. Phys. Chem. B, 2001, vol. 105, p. 6798.

    Article  CAS  Google Scholar 

  50. Wyman, J., Chem. Rev., 1936, vol. 19, p. 213.

    Article  CAS  Google Scholar 

  51. Yu, L., Lu, T., Luan, Y.X., Liu, J., and Xu, G.Y., Colloids Surf. A, 2005, vol. 257–258, p. 375.

    Article  Google Scholar 

  52. Rakshit, A.K. and Sharma, B., Colloid Polym. Sci., 2003, vol. 281, p. 45.

    Article  CAS  Google Scholar 

  53. Ray, G.B., Ghosh, S., and Moulik, S.P., J. Surf. Deterg., 2009, vol. 12. p. 131.

    Article  CAS  Google Scholar 

  54. Mehta, S.K., Bhasin, K.K., Chauhan, R., and Dham, S., Colloids Surf. A, 2005, vol. 255, p. 153.

    Article  CAS  Google Scholar 

  55. Mukerjee, P., Mysels, K.J., and Kapauan, P., J. Phys. Chem., 1967, vol. 71, p. 4166.

    Article  CAS  Google Scholar 

  56. Vasilescu, M., Angelescu, D., Almgren, M., and Valstar, A., Langmuir, 1999, vol. 15, p. 2635.

    Article  CAS  Google Scholar 

  57. Behera, K., Dahiya, P., and Pandey, S., J. Colloid Interface Sci., 2007, vol. 316, p. 803.

    Article  CAS  Google Scholar 

  58. Kalyanasundaram, K. and Thomas, J.K., J. Am. Chem. Soc., 1977, vol. 99, p. 2039.

    Article  CAS  Google Scholar 

  59. Baker, G.A., Pandey, S., and Baker, S.N., Analyst, 2004, vol. 129, p. 890.

    Article  CAS  Google Scholar 

  60. Bazito, R.C. and El Seoud, O.A.., Langmuir, 2002, vol. 18, p. 4362.

    Article  CAS  Google Scholar 

  61. Turro, N.J. and Yekta, A., J. Am. Chem. Soc., 1978, vol. 100, p. 5951

    Article  CAS  Google Scholar 

  62. Sabate, R. and Estelrich, J., J. Phys. Chem. B, 2003, vol. 107, p. 4137

    Article  CAS  Google Scholar 

  63. Tachiya, M., Chem. Phys. Lett., 1975, vol. 33, p. 289

    Article  CAS  Google Scholar 

  64. Tachiya, M., J. Chem. Phys., 1982, vol. 76, p. 340.

    Article  CAS  Google Scholar 

  65. Chakraborty, H. and Sarkar, M., J. Colloid Interface Sci., 2005, vol. 292, p. 265.

    Article  CAS  Google Scholar 

  66. Aswal, V.K. and Goyal, P.S., Chem. Phys. Lett., 2002, vol. 364, p. 44.

    Article  CAS  Google Scholar 

  67. Israelachvili, J.N., Intermolecular and Surface Forces, Second ed., London: Academic Press, 1991, p. 370.

    Google Scholar 

  68. Das, D. and Ismail, K., J. Colloid Interface Sci., 2008, vol. 327, p. 198.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Jamia Millia Islamia (Central University), New Delhi, 110025, India

    A. Ali, V. Bhushan & N. A. Malik

  2. Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas Delhi, 110016, India

    K. Behera

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  1. A. Ali
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  2. V. Bhushan
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  3. N. A. Malik
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  4. K. Behera
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Ali, A., Bhushan, V., Malik, N.A. et al. Study of mixed micellar aqueous solutions of sodium dodecyl sulfate and amino acids. Colloid J 75, 357–365 (2013). https://doi.org/10.1134/S1061933X13040029

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