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Effect of IR Radiation on the Properties of Polyacrylonitrile and Membranes on Its Basis

  • Polymeric Membranes
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Abstract

The effect of processing of polyacrylonitrile membranes by IR radiation at a temperature of 100–150°С is studied. The influence of the processing temperature on the film structure is ascertained. In a film heated at 100°С, a small amount of the double C=N bonds is found. Its further heating to 120°С is accompanied by a change in the chain conformation and an increase in the content of C=N bonds. It is shown that, upon IR processing at 120°С, polyacrylonitrile ceases to dissolve in N-methylpyrrolidone, dimethylacetamide, dimethylformamide, and dimethyl sulfoxide. Heating at 150°С gives rise to the appearance of conjugated С=N–C=N bonds. The analysis of AFM micrographs demonstrates that the processing of the membranes by IR radiation makes their surface rougher, while the size of pores changes slightly. The permeability of the membranes in various media is measured.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    A. A. Yushkin, M. N. Efimov, A. A. Vasil’ev, G. P. Karpacheva, G. N. Bondarenko & A. V. Volkov

  2. Gubkin State University of Oil and Gas (National Research University), Moscow, 119991, Russia

    V. I. Ivanov

  3. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    Yu. G. Bogdanova & V. D. Dolzhikova

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  1. A. A. Yushkin
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  2. M. N. Efimov
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  3. A. A. Vasil’ev
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  5. Yu. G. Bogdanova
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  6. V. D. Dolzhikova
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  8. G. N. Bondarenko
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  9. A. V. Volkov
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Correspondence to A. A. Yushkin.

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Original Russian Text © A.A. Yushkin, M.N. Efimov, A.A. Vasil’ev, V.I. Ivanov, Yu.G. Bogdanova, V.D. Dolzhikova, G.P. Karpacheva, G.N. Bondarenko, A.V. Volkov, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2017, Vol. 59, No. 6, pp. 548–558.

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Yushkin, A.A., Efimov, M.N., Vasil’ev, A.A. et al. Effect of IR Radiation on the Properties of Polyacrylonitrile and Membranes on Its Basis. Polym. Sci. Ser. A 59, 880–890 (2017). https://doi.org/10.1134/S0965545X17060104

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  • DOI: https://doi.org/10.1134/S0965545X17060104

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