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Features of the formation of interpolymer complexes of poly(carboxylic acids) and nonionic polymers in aqueous solutions in the presence of low-molecular-mass electrolytes

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Abstract

The published experimental data on the interpolymer reactions that involve nonionic polymers and poly(carboxylic acids) in aqueous solutions in the presence of low-molecular-mass electrolytes have been analyzed. A theoretical approach that allows one to interpret the character and direction of a shift in the critical pH values of the complexation reaction due to the effect of low-molecular-mass electrolyte has been proposed. It has been found that the character of interactions between poly(carboxylic acids) and nonionic polymers in the presence of a low-molecular-mass salt is significantly influenced by the processes of local ion exchange resulting in the heterogeneous distribution of low-molecular-mass ions throughout the solution volume.

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Authors and Affiliations

  1. Al-Farabi Kazakh National University, Kazakh, 050040, Kazakhstan

    G. A. Mun, B. B. Yermukhambetova, N. A. Vorob’eva & G. S. Irmukhametova

  2. Almaty University of Power Engineering and Telecommunications, Almaty, 050012, Kazakhstan

    I. E. Suleimenov

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  1. G. A. Mun
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  2. I. E. Suleimenov
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  3. B. B. Yermukhambetova
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  4. N. A. Vorob’eva
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  5. G. S. Irmukhametova
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Correspondence to G. A. Mun.

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Original Russian Text © G.A. Mun, I.E. Suleimenov, B.B. Yermukhambetova, N.A. Vorob’eva, G.S. Irmukhametova, 2016, published in Vysokomolekulyarnye Soedineniya, Seriya A, 2016, Vol. 58, No. 6, pp. 625–638.

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Mun, G.A., Suleimenov, I.E., Yermukhambetova, B.B. et al. Features of the formation of interpolymer complexes of poly(carboxylic acids) and nonionic polymers in aqueous solutions in the presence of low-molecular-mass electrolytes. Polym. Sci. Ser. A 58, 944–955 (2016). https://doi.org/10.1134/S0965545X16060134

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  • DOI: https://doi.org/10.1134/S0965545X16060134

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