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Heterogeneous Epoxidation of α-Pinene with Air over Mordenite (MOR) Supported Cobalt Complex

  • PHYSICAL CHEMISTRY OF SEPARATION PROCESSES. CHROMATOGRAPHY
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Abstract

The MOR supported cobalt complex materials were synthesized by ion exchange method and used to catalyze the epoxidation reaction of α-pinene with air. The liquid phase batch mode of epoxidation reaction was carried out under atmospheric pressure and aerobic conditions. Among the supported [Co(NH3)6]3+-zeolites catalysts, [Co(NH3)6]3+-MOR exhibited the best catalytic efficiency for the titled reaction, and high reaction conversion as well as epoxidation product selectivity were obtained for α-pinene and α-epoxypinane. Parametric studies were performed to examine the effect factors like the Co content, the solvent, the initiator, the substrate amount and the catalyst amount. The catalyst can be reused at least nine cycles without significant loss in activity towards epoxidation.

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ACKNOWLEDGMENTS

The authors acknowledge the National Natural Science Foundation of China (22072038, U20A20122), the Hubei Student Innovation and Entrepreneurship Foundation of China (S202010512082, S201910512016), and Applied Basic Frontier Project of Wuhan Science and Technology Bureau (2019010701011415).

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Authors and Affiliations

  1. Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Ministry-of-Education Key Laboratory for Green Preparation and Application of Functional Materials, Hubei University, 430062, Wuhan, China

    Xixi Li, Xinhuan Lu, Run Jing, Haifu Zhang, Chenlong Wang, Beibei Wang, Dan Zhou & Qinghua Xia

  2. Jingchu University of Technology, 448000, Jingmen, China

    Huaxin Zhang

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  1. Xixi Li
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  2. Xinhuan Lu
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  3. Run Jing
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  4. Haifu Zhang
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  5. Chenlong Wang
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  6. Huaxin Zhang
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  9. Qinghua Xia
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Correspondence to Xinhuan Lu or Qinghua Xia.

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Li, X., Lu, X., Jing, R. et al. Heterogeneous Epoxidation of α-Pinene with Air over Mordenite (MOR) Supported Cobalt Complex. Russ. J. Phys. Chem. 96, 2747–2756 (2022). https://doi.org/10.1134/S0036024422120317

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