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Thermophysical Properties of Binary Mixtures of Diisopropyl Ether with Methyl Benzoate, Ethyl Benzoate, and Benzyl Acetate at Various Temperatures

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Abstract

Densities and viscosities of binary mixtures of diisopropyl ether (DIPE) with methyl benzoate (MB), ethyl benzoate (EB) and benzyl acetate (BA) were measured experimentally at T = (298.15, 303.15, 308.15, and 313.15) K and P = 0.1 MPa for the entire composition range. The estimated values of the pure liquids and mixtures were subsequently used to determine the properties such as excess molar volume (VE), deviation in viscosity (∆η), and excess Gibbs free energy (∆G*E). These results were fitted into Redlich–Kister polynomial equation to calculate the coefficients and standard errors.

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Abbreviations

ρ:

density (g/cm3);

η:

dynamic viscosity (mPa s);

V E :

excess molar volume (cm3/mol);

∆η:

viscosity deviation (mPa s);

∆G*E :

excess Gibbs free energy of activation flow (J/mol).

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ACKNOWLEDGMENTS

I express my sincere gratitude to the management of Sathyabama Institute of Science and Technology for availing research facilities to carry out and publish this work.

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Authors and Affiliations

  1. Department of Chemical Engineering, Sathyabama Institute of Science and Technology, 600119, Chennai, India

    D. Venkatesan & D. Joshua Amarnath

  2. Department of Engineering, College of Applied Sciences, Sohar, MoHE, Oman

    K. Saravanakumar

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  1. D. Venkatesan
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  2. D. Joshua Amarnath
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  3. K. Saravanakumar
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Correspondence to D. Venkatesan.

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Venkatesan, D., Amarnath, D.J. & Saravanakumar, K. Thermophysical Properties of Binary Mixtures of Diisopropyl Ether with Methyl Benzoate, Ethyl Benzoate, and Benzyl Acetate at Various Temperatures. Russ. J. Phys. Chem. 94, 1573–1580 (2020). https://doi.org/10.1134/S0036024420080300

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