Skip to main content
Log in

Chain-Thermal Explosions and the Transition from Deflagration Combustion to Detonation

  • Chemical Kinetics and Catalysis
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The transition from combustion to a chain-thermal explosion, a necessary step in the transition from deflagration combustion into detonation, is studied using the example of hydrogen oxidation. Differences between the kinetic modes of ignition and a chain-thermal explosion are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. N. N. Semenov, On Some Problems of Chemical Kinetics and Reactivity (Akad. Nauk SSSR, Moscow, 1958) [in Russian].

    Google Scholar 

  2. D. A. Frank-Kamenetskii, Diffusion and Heat Exchange in Chemical Kinetics (Nauka, Moscow, 1987; Springer, Heidelberg, 1995).

    Google Scholar 

  3. Ya. B. Zel’dovich, G. A. Barenblatt, V. B. Librovich, and D. V. Makhviladze, Mathematical Theory of Combustion and Explosions (Akad. Nauk SSSR, Moscow, 1980; Plenum, New York, 1985).

    Google Scholar 

  4. Great Russian Encyclopedy (2006), Vol. 5, p. 242 [in Russian].

  5. S. G. Andreev, M. M. Boiko, and V. V. Selivanov, Experimental Method of Explosion Physics (Fizmatlit, Moscow, 2013) [in Russian].

    Google Scholar 

  6. Ya. B. Zel’dovich and A. S. Kompaneets, Detonation Theory (Nauka, Moscow, 1958) [in Russian].

    Google Scholar 

  7. B. Lewis and G. von Elbe, Combustion, Explosions, and Flame in Gases (Academic, New York, 1987).

    Google Scholar 

  8. S. M. Frolov and V. S. Ivanov, Deflagranive and Detonanive Combustion (Torus, Moscow, 2010), p. 133.

    Google Scholar 

  9. N. N. Smirnov, V. F. Nikitin, and Yu. G. Phylippov, J. Eng. Phys. Thermophys. 83, 1287 (2010).

    Article  CAS  Google Scholar 

  10. E. S. Oran and V. N. Gamezo, Combust. Flame 148, 4 (2007).

    Article  CAS  Google Scholar 

  11. V. V. Azatyan, Kinet. Catal. 37, 480 (1996).

    CAS  Google Scholar 

  12. V. V. Azatyan, Kinet. Catal. 56, 1 (2015).

    Article  CAS  Google Scholar 

  13. V. V. Azatyan, Z. S. Andrianova, A. N. Ivanova, A. A. Karnaukh, and V. A. Pavlov, Russ. J. Phys. Chem. A 89, 1753 (2015).

    Article  CAS  Google Scholar 

  14. V. V. Azatyan, Kinet. Katal. 17, 533 (1976).

    CAS  Google Scholar 

  15. V. V. Azatyan, A. A. Shavard, V. A. Kalkanov, and A. G. Merzhanov, Khim. Fiz. 6, 1696 (1987).

    CAS  Google Scholar 

  16. V. V. Azatyan, I. A. Bolod’yan, S. N. Kopylov, et al., Fiz. Goreniya Vzryva 37 (5), 12 (2001).

    CAS  Google Scholar 

  17. V. V. Azatyan, V. A. Pavlov, and O. P. Shatalov, Kinet. Catal. 46, 789 (2005).

    Article  CAS  Google Scholar 

  18. V. V. Azatyan, S. K. Abramov, V. M. Prokopenko, V. I. Ratnikov, and Yu. V. Tunik, Kinet. Catal. 54, 523 (2013).

    Article  CAS  Google Scholar 

  19. V. V. Azatyan, Z. S. Andrianova, and A. N. Ivanova, Kinet. Catal. 51, 337 (2010).

    Article  CAS  Google Scholar 

  20. N. M. Chirkov, Acta Physicochim. URSS 6, 915 (1937).

    CAS  Google Scholar 

  21. M. S. Ziskin, Dokl. Akad. Nauk SSSR 34, 279 (1941).

    Google Scholar 

  22. D. A. Frank-Kamenetskii, Zh. Fiz. Khim. 13, 738 (1939).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Azatyan.

Additional information

Original Russian Text © V.M. Prokopenko, V.V. Azatyan, 2018, published in Zhurnal Fizicheskoi Khimii, 2018, Vol. 92, No. 1, pp. 51–55.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Prokopenko, V.M., Azatyan, V.V. Chain-Thermal Explosions and the Transition from Deflagration Combustion to Detonation. Russ. J. Phys. Chem. 92, 42–46 (2018). https://doi.org/10.1134/S0036024418010193

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024418010193

Keywords

Navigation