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The dependence of the rules governing gas-phase combustion on the competition between chain propagation and chain termination reactions

  • Chemical Kinetics and Catalysis
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Abstract

The competition between chain propagation and chain termination reactions was shown to play an important role in gas-phase combustion. Conditions under which this competition to a substantial extent determined the critical ignition conditions and the rate of the process were analyzed. Examples that showed that ignoring the role played by chain propagation, chain termination, and chain branching reactions in branched-chain processes led to conclusions that contradicted experimental data were considered.

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References

  1. N. N. Semenov, Chain Reactions (Goskhimtekhizdat, Leningrad, 1934) [in Russian].

    Google Scholar 

  2. N. N. Semenov, On Some Problems of Chemical Kinetics and Reaction Ability (Akad. Nauk SSSR, Moscow, 1958) [in Russian].

    Google Scholar 

  3. N. N. Semenov, Development of Chain Reaction Theory and Thermal Explosion (Mysl’, Moscow, 1969) [in Russian].

    Google Scholar 

  4. D. A. Frank-Kamenetskii, Diffusion and Heat Transfer in Chemical Kinetics (Nauka, Moscow, 1987) [in Russian].

    Google Scholar 

  5. Chemical Encyclopedy (Sov. Entsiklopediya, Moscow, 1988), Vol. 1 [in Russian].

  6. Physical Encyclopedy (Sov. Entsiklopediya, Moscow, 1988), Vol. 1 [in Russian].

  7. B. Lewis and G. Elbe, Combustion, Flames, and Explosions of Gases (Academic, New York, 1987; Mir, Moscow, 1968).

    Google Scholar 

  8. Chemical Encyclopedy (Bol’sh. Ros. Entsiklopediya, Moscow, 1998), Vol. 5, p. 682 [in Russian].

  9. J. Warnatz, U. Maas, and R. Dibba, Combustion. Physical and Chemical Aspects, Modeling, Experiments, Formation of Pollutants (Springer, Berlin, 2001; Fizmatlit, Moscow, 2003).

    Google Scholar 

  10. A. P. Purmal’, A, B, C... of Chemical Kinetics (Akademkniga, Moscow, 2004) [in Russian].

    Google Scholar 

  11. L. D. Petrova, V. V. Azatyan, A. N. Baratov, et al., Combustion and Explosion (Nauka, Moscow, 1976), p. 526 [in Russian].

    Google Scholar 

  12. V. V. Azatyan, N. V. Andreeva, and A. I. El’natanov, Khim. Fiz. 7, 821 (1988).

    CAS  Google Scholar 

  13. V. V. Azatyan, Pozharovzryvobezopasnost’ 3(4), 13 (1994).

    Google Scholar 

  14. V. V. Azatyan, Usp. Khim. 68, 1122 (1999).

    Google Scholar 

  15. V. V. Azatyan, V. A. Pavlov, and V. A. Shatalov, Kinet. Katal. 48, 835 (2006) [Kinet. Catal. 48, 789 (2006)].

    Google Scholar 

  16. N. M. Emanuel’ and D. G. Knorre, Course of Chemical Kinetics (Vyssh. Shkola, Moscow, 1984) [in Russian].

    Google Scholar 

  17. D. L. Baulch, C. T. Bowman, C. J. Cobos, et al., J. Phys. Chem. Ref. Data 34, 757 (2005).

    Article  CAS  Google Scholar 

  18. V. N. Panfilov, Yu. D. Tsvetkov, and V. V. Voevodskii, Kinet. Katal. 1, 233 (1960).

    Google Scholar 

  19. V. V. Azatyan, V. N. Panfilov, and A. B. Nalbandyan, Kinet. Katal. 2, 295 (1961).

    CAS  Google Scholar 

  20. V. V. Azatyan, L. A. Akopyan, P. B. Nalbandyan, and B.V. Ozherel’ev, Dokl. Akad. Nauk SSSR 141, 129 (1961).

    CAS  Google Scholar 

  21. V. P. Balakhnin, Yu. M. Gershenzon, V. N. Kondrat’ev, and A. B. Nalbandyan, Dokl. Akad. Nauk SSSR 154, 1142(1964).

    CAS  Google Scholar 

  22. O. P. Korobeinichev and I. V. Ribatskaya, et al., “Inhibition of Atmospheric Pressure, H2/O2/N2 Flames by Trimethylphosphate over Range of Equivalence Ratio,” Proc. of Combust. Inst. (2009).

  23. D. L. Baulch, C. J. Cobos, R. A. Cox, et al., Combust. Flame 98, 441(1994).

    Article  Google Scholar 

  24. V. N. Kondrat’ev and E. E. Nikitin, Kinetics and Mechanism of Gas-Phase Reactions (Nauka, Moscow, 1981) [in Russian].

    Google Scholar 

  25. H. R. Heiple and B. Lewis, J. Chem. Phys. 9, 584 (1941).

    Article  CAS  Google Scholar 

  26. V. V. Azatyan, K. N. Gaganidze, S. A. Kolesnikov, and G. R. Trubnikov, Kinet. Katal. 23, 244 (1982).

    CAS  Google Scholar 

  27. N. N. Semenov, On Chain Reactions and Combustion (Znanie, Moscow, 1957) [in Russian].

    Google Scholar 

  28. N. N. Semenov and V. V. Azatyan, in Combustion and Explosion (Nauka, Moscow, 1971), p. 258 [in Russian].

    Google Scholar 

  29. V. V. Azatyan and N. N. Semenov, Kinet. Katal. 13(1), 17(1972).

    CAS  Google Scholar 

  30. V. V. Azatyan, M. U. Kislyuk, I. I. Tret’yakov, and A. A. Shavard, Kinet. Katal. 21, 583(1980).

    CAS  Google Scholar 

  31. V. V. Azatyan, N. M. Rubtsov, G. I. Tsvetkov, and V. I. Chernysh, Zh. Fiz. Khim. 79, 397 (2005) [Russ. J. Phys. Chem. A 79, 320 (2005)].

    Google Scholar 

  32. A. N. Ivanova, Z. S. Andrianova, and V. V. Azatyan, Khim. Fiz. 17(8), 91 (1998).

    CAS  Google Scholar 

  33. V. V. Voevodskii and V. N. Kondratyev, Progr. Chem. Kinet. 1, 42(1961).

    Google Scholar 

  34. A. B. Nalbandyan and V. V.Voevodskii, Mechanism of the Oxidation and Combustion of Hydrogen (Akad. Nauk SSSR, Moscow, 1948) [in Russian].

    Google Scholar 

  35. N. N. Semenov, Dokl. Akad. Nauk SSSR 81, 645 (1951).

    CAS  Google Scholar 

  36. V. V. Azatyan, Zh. Fiz. Khim. 80, 1 (2006).

    Google Scholar 

  37. V. V. Azatyan, I. A. Bolod’yan, V. Yu. Navtsenya, and Yu. N. Shebeko, Zh. Fiz. Khim. 76, 775 (2002).

    CAS  Google Scholar 

  38. V. V. Azatyan and A. G. Merzhanov, Khim. Fiz. 27(11), 93 (2008).

    CAS  Google Scholar 

  39. V. V. Azatyan, T. G. Mkryan, E. N. Sarkisyan, and S. A. Chobanyan, Khim. Fiz. 10(10), 336 (1991).

    CAS  Google Scholar 

  40. E. N. Sarkisyan, A. A. Borisov, and V. V. Azatyan, Khim. Fiz. 18(5), 49 (1999).

    CAS  Google Scholar 

  41. A. N. Ivanova and B. L. Ternopol’skii, Kinet. Katal. 20, 1541 (1979).

    CAS  Google Scholar 

  42. V. V. Azatyan, Kinet. Katal. 18, 282 (1977).

    CAS  Google Scholar 

  43. V. M. Kislov, E. A. Salgansky, and G. B. Manelis, in Proc. of Intern. Seminar on Nonequilibrium Processes (Torus, Moscow, 2005), p. 247.

    Google Scholar 

  44. S. S. Kostenko, E. V. Polianchuk, A. A. Karnaukh, et al., in Proc. of Intern. Seminar on Nonequilibrium Processes (Torus, Moscow, 2005), p. 223.

    Google Scholar 

  45. V. V. Azatyan, I. M. Naboko, V. Ya. Petukhov, et al., Dokl. Akad. Nauk SSSR 394, 61 (2004).

    Google Scholar 

  46. V. V. Azatyan, M. U. Kislyuk, I. I. Tret’yakov, and A. A. Shavard, Kinet. Katal. 21, 583 (1980).

    CAS  Google Scholar 

  47. V. V. Azatyan, N. M. Rubtsov, G. I. Tsvetkov, and V I. Chernysh, Zh. Fiz. Khim. 79, 397 (2005).

    Google Scholar 

  48. E. N. Aleksandrov, N. M. Kuznetsov, and S. N. Kozlov, Fiz. Goren. Vzryva 43(5), 44 (2007).

    CAS  Google Scholar 

  49. E. N. Aleksandrov and N. M. Kuznetsov, Nauka Tekh-nol. Promyshl., Nos. 1-2, 120 (2007).

    Google Scholar 

  50. R. Wood, Physical Optics (Macmillan, New York, 1934; Inostr. Liter., Moscow, 1934; 1933).

    Google Scholar 

  51. N. N. Semenov, Chain Reactions (Nauka, Moscow, 1996), pp. 406, 410, 411 [in Russian].

    Google Scholar 

  52. E. N. Aleksandrov Fiz. Goren. Vzryva 42(2), 10 (2006).

    CAS  Google Scholar 

  53. E. N. Aleksandrov, V. S. Arutyunov, V. V. Dubrovina, and S. N. Kozlov, Zh. Fiz. Khim. 57, 2448 (1983).

    CAS  Google Scholar 

  54. V. V. Azatyan, G. A. Arutyunyan, Z. G. Dzotsenidze, et al., Zh. Fiz. Khim. 61, 3151 (1987).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Structural Macrokinetics and Materials Science Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Azatyan

  2. Federal State Enterprise All-Russia Research Institute for Fire Protection, Balashikha, Moscow oblast, Russia

    I. A. Bolod’yan, V. Yu. Navtsenya & Yu. N. Shebeko

Authors
  1. V. V. Azatyan
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  2. I. A. Bolod’yan
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  3. V. Yu. Navtsenya
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  4. Yu. N. Shebeko
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Corresponding author

Correspondence to V. V. Azatyan.

Additional information

Original Russian Text © V. V. Azatyan, I.A. Bolod’yan, V. Yu. Navtsenya, Yu.N. Shebeko, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 3, pp. 447–455.

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Azatyan, V.V., Bolod’yan, I.A., Navtsenya, V.Y. et al. The dependence of the rules governing gas-phase combustion on the competition between chain propagation and chain termination reactions. Russ. J. Phys. Chem. 84, 383–390 (2010). https://doi.org/10.1134/S0036024410030076

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  • DOI: https://doi.org/10.1134/S0036024410030076

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