Abstract
The results of a Mössbauer study of hyperfine interactions of 57Fe probe nuclei in isostructural hexagonal manganites h-ScMnO3 and h-InMnO3 are presented. The results of measurements of the Mössbauer spectra at T > TN, as well as calculations of the parameters of the electric field gradient tensor at 57Fe nuclei, demonstrated different behavior of the probe iron ions in these isostructural systems, reflecting the difference in the processes of defect formation in their crystal lattices. On the contrary, measurements at T < TN did not reveal any differences in the local magnetic structure of 57Fe probe atoms in these oxides.
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REFERENCES
W. C. Koehler, H. L. Yakel, E. O. Wollan, et al., Phys. Lett. A. 9, 93 (1964). https://doi.org/10.1016/0031-9163(64)90089-7
V. E. Wood, A. E. Austin, E. W. Collings, et al., Phys. Chem. Solids 34, 859 (1973). https://doi.org/10.1016/S0022-3697(73)80088-5
M. Fiebig, D. Frohlich, T. Lottermoser, et al., Phys. Rev. B 65, 224421 (2002). https://doi.org/10.1103/PhysRevB.65.224421
A. Munoz, J. A. Alonso, M. J. Matinez-Lope, et al., Phys. Rev. B 62, 9498 (2000). https://doi.org/10.1103/PhysRevB.62.9498
B. Lorenz, ISRN Condens. Matter. Phys. 2013, 497073 (2013). https://doi.org/10.1155/2013/497073
K. Uusi-Esko, Diss. for the Degree of Doctor of Science in Technology, Aalto University Press, Helsinki (2011).
K. Uusi-Esko, J. Malm, N. Imamura, et al., M. Mater. Chem. Phys. 112, 1029 (2008). https://doi.org/10.1016/j.matchemphys.2008.07.009
H. L. Yakel, W. C. Koehler, E. F. Bertaut, et al., Acta Crystallogr. 16, 957 (1963). https://doi.org/10.1107/S0365110X63002589
O. M. Fedorova, V. F. Balakirev, and Y. V. Golikov, Russ. J. Inorg. Chem. 56, 173 (2011). https://doi.org/10.1134/S0036023611020070
M. A. Gilleo, Acta Crystallogr. 10, 161 (1957). https://doi.org/10.1107/S0365110X57000535
H. L. Yakel, Acta Crystallogr. 8, 394 (1955). https://doi.org/10.1107/S0365110X55001291
A. A. Belik, S. Kamba, M. Savinov, et al., Phys. Rev. B 79, 054411 (2009). https://doi.org/10.1103/PhysRevB.79.054411
J. E. Greedan, M. Bieringer, J. F. Britten, et al., J. Solid State Chem. 116, 118 (1995). https://doi.org/10.1006/jssc.1995.1192
X. Fabreges, I. Mirebeau, S. Petit, et al., Phys. Rev. B 84, 054455 (2011). https://doi.org/10.1103/PhysRevB.84.054455
W. Yi, I. A. Presniakov, A. V. Sobolev, et al., Sci. Technol. Adv. Mater. 16, 024801 (2015). https://doi.org/10.1088/1468-6996/16/2/024801
I. S. Glazkova, A. V. Sobolev, W. Yi, et al., J. Exp. Theor. Phys. 126, 514 (2018). https://doi.org/10.1134/S1063776118030135
I. S. Glazkova, M. N. Smirnova, O. N. Kondrat’eva, et al., Russ. J. Inorg. Chem. 68 (2023). https://doi.org/10.1134/S0036023623600387
Yu. A. Teterin, M. N. Smirnova, K. I. Maslakov, et al., Russ. J. Inorg. Chem. 68, 801 (2023). https://doi.org/10.1134/S0036023623600831
H. Chen, T. Yu, and P. Gao, Inorg. Chem. 52, 9692 (2013). https://doi.org/10.1021/ic4016838
V. Petricek, M. Dusek, and L. Palatinus, Z. Crystallogr. 229, 345 (2014). https://doi.org/10.1515/zkri-2014-1737
E. Cockayne, I. Levin, H. Wu, et al., Phys. Rev. B 87, 184413 (2013). https://doi.org/10.1103/PhysRevB.87.184413
M. F. Bekheet, I. Svoboda, N. Liu, et al., J. Solid State Chem. 241, 54 (2016). https://doi.org/10.1016/j.jssc.2016.05.031
A. V. Sobolev, A. A. Akulenko, I. S. Glazkova, et al., J. Phys. Chem. C 122, 19767 (2018). https://doi.org/10.1021/acs.jpcc.8b05516
M. E. Matsnev and V. S. Rusakov, AIP Conf. Proc. 1489, 178 (2012). https://doi.org/10.1063/1.4759488
F. Menil, J. Phys. Chem. Solids 46, 763 (1985). https://doi.org/10.1016/0022-3697(85)90001-0
I. A. Presniakov, V. S. Rusakov, T. V. Gubaidulina, et al., Phys. Rev. B 76, 214407 (2007). https://doi.org/10.1103/PhysRevB.76.214407
Y. S. Glazkova, N. Terada, Y. Matsushita, et al., Inorg. Chem. 54, 9081 (2015). https://doi.org/10.1021/acs.inorgchem.5b01472
S. J. Kim, G. Demazeau, I. A. Presnyakov, et al., Russ. J. Inorg. Chem. 48, 1394 (2003).
I. A. Presnyakov, V. S. Rusakov, A. V. Sobolev, et al., Russ. J. Inorg. Chem. 54, 1957 (2009). https://doi.org/10.1134/S0036023609120195
A. A. Belik, Y. Matsushita, M. Tanaka, et al., Angew. Chem., Int. Ed. Engl. 49, 7723 (2010). https://doi.org/10.1002/anie.201003080
R. D. Shannon and R. X. Fischer, Phys. Rev. B 73, 235111 (2006). https://doi.org/10.1103/PhysRevB.73.235111
A. V. Sobolev, E. S. Kozlyakova, I. S. Glazkova, et al., J. Phys. Chem. C 122, 19746 (2018). https://doi.org/10.1021/acs.jpcc.8b05122
M. Azuma, K. Takata, T. Saito, et al., J. Am. Chem. Soc. 127, 8889 (2005). https://doi.org/10.1021/ja0512576
W. Yi, A. J. Princep, Y. Guo, et al., Inorg. Chem. 54, 8012 (2015). https://doi.org/10.1021/acs.inorgchem.5b01195
I. Yamada, M. Murakami, N. Hayashi, et al., Inorg. Chem. 55, 1715 (2016). https://doi.org/10.1021/acs.inorgchem.5b02623
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The work was supported by the Russian Science Foundation (project no. 19-73-10034).
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Translated by G. Kirakosyan
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Sobolev, A.V., Šandalova, S., Smirnova, M.N. et al. Structure of the Local Environment and Hyperfine Interactions of 57Fe Probe Nuclei in AMnO3 (A = Sc, In). Russ. J. Inorg. Chem. 68, 1349–1356 (2023). https://doi.org/10.1134/S0036023623601812
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DOI: https://doi.org/10.1134/S0036023623601812