Skip to main content
SpringerLink
Log in

Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties

  • COORDINATION COMPOUNDS
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

The reaction of barium(II) hydroxide with 2-furoic acid (pyromucic acid, Hfur) gave 1D coordination polymer {[Ba3(fur)6(Hfur)2(H2O)8]}n·4nH2O (I). According to X-ray diffraction data, I contains two symmetrically independent barium cations, which have different environments: Ba(1) coordinates six fur– anions, while Ba(2) is a fragment of heteroleptic coordination (fur–, Hfur, and H2O) (CIF file CCDC no. 2063380). The supramolecular polymeric architecture of I is determined by bridging water molecules and numerous hydrogen bonds between coordinated and solvation water molecules to form a 1D motif. The arrangement of Ba2+ ions in the trinuclear moiety {Ba3(fur)6(Hfur)2(H2O)8} of the polymer is nearly linear. The thermal behavior of I, investigated by simultaneous thermal analysis (argon atmosphere), showed a stepwise character of thermal decomposition caused by gradual destruction of the hydrogen-bonded framework and the subsequent partial destruction of the organic part. Analysis of the biological activity of I against the non-pathogenic Mycolicibacterium smegmatis strain showed low sensitivity of the bacterial wall to the complex.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. K. D. A. Dimé, H. Cattey, D. Lucas, and Ch. H. Devillers, Eur. J. Inorg. Chem. 2018, 4834 (2018). https://doi.org/10.1002/ejic.201801142

    Article  Google Scholar 

  2. J. Bhattacharjee, A. Harinath, A. Sarkar, and T. K. Panda, ChemCatChem 11, 3366 (2019). https://doi.org/10.1002/cctc.201900920

    Article  CAS  Google Scholar 

  3. S. Nandi, Ph. Luna, R. Maity, et al., Mater. Horiz. 6, 1883 (2019). https://doi.org/10.1039/C9MH00133F

    Article  CAS  Google Scholar 

  4. B. Paluchowska, J. K. Maurin, and J. Leciejewicz, J. Chem. Crystallogr. 27, 177 (1997). https://doi.org/10.1007/BF02575986

    Article  CAS  Google Scholar 

  5. J. Yang, Yin Xin, Wu Le, et al., Inorg. Chem. 57, 150105 (2019). https://doi.org/10.1021/acs.inorgchem.5b00113

    Article  CAS  Google Scholar 

  6. Wan Ke-Ke, Yu Jie-Hui, Yang Qing-Feng, et al., Eur. J. Inorg. Chem. 3094 (2019). https://doi.org/10.1002/ejic.201900558

  7. H. Roueindeji, A. Ratsifitahina, and T. Roisnel, Chem. - Eur. J. 25, 8854 (2019). https://doi.org/10.1002/chem.201901262

    Article  CAS  PubMed  Google Scholar 

  8. T. Maity and D. Saha, S. Das, et al., Eur. J. Inorg. Chem. 30, 4914 (2012). https://doi.org/10.1002/ejic.201200417

    Article  CAS  Google Scholar 

  9. X. Xu, F. Hu, and Q. Shuai, New J. Chem. 41, 13319 (2017). https://doi.org/10.1039/C7NJ03046K

    Article  CAS  Google Scholar 

  10. W. Su, Y. Shi, X. Hao, et al., Inorg. Chim. Acta 490, 29 (2019). https://doi.org/10.1016/j.ica.2019.02.037

    Article  CAS  Google Scholar 

  11. F. Liu, Y. Xu, L. Zhao, et al., J. Mater. Chem. A 3, 21545 (2015). https://doi.org/10.1039/C5TA03680A

    Article  CAS  Google Scholar 

  12. L. E. Kreno, K. Leong, O. K. Farha, et al., Chem. Rev. 112, 1105 (2012). https://doi.org/10.1021/cr200324t

    Article  CAS  PubMed  Google Scholar 

  13. J. H. Wang, M. Li, and D. Li, Chem. Sci. 4, 1793 (2013). https://doi.org/10.1039/C3SC00016H

    Article  CAS  Google Scholar 

  14. J. Xiao, Y. Wu, M. Li, et al., Chem. - Eur. J. 19, 1891 (2013). https://doi.org/10.1002/chem.201203515

    Article  CAS  PubMed  Google Scholar 

  15. D. A. Murav’eva, I. A. Samylina, and G. P. Yakovleva, Pharmacognosy (Meditsina, Moscow, 2007) [in Russian].

    Google Scholar 

  16. E. Bartolome, J. Bartolome, S. Melnic, et al., Dalton Trans. 43, 10999 (2014). https://doi.org/10.1039/C4DT00538D

    Article  CAS  PubMed  Google Scholar 

  17. P. H. Bhargao and B. R. Srinivasan, J. Coord. Chem. 72, 2599 (2019). https://doi.org/10.1080/00958972.2019.1666980

    Article  CAS  Google Scholar 

  18. G. M. Sheldrick, Acta Crystallogr., Sect. A 71, 3 (2015). https://doi.org/10.1107/S2053273314026370

    Article  CAS  Google Scholar 

  19. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009). https://doi.org/10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  20. S. F. Chabira and M. Sebaa, Rev. Sci. Technol. Synthèse 24, 44 (2012).

    Google Scholar 

  21. O. B. Bekker, D. N. Sokolov, O. A. Luzina, et al., Med. Chem. Res. 24, 2926 (2015). https://doi.org/10.1007/s00044-015-1348-2

    Article  CAS  Google Scholar 

  22. I. A. Lutsenko, D. S. Yambulatov, M. A. Kiskin, et al., Chem. Select 5, 11837 (2020). https://doi.org/10.1002/slct.202003101

    Article  CAS  Google Scholar 

  23. I. A. Lutsenko, D. E. Baravikov, M. A. Kiskin, et al. Russ. J. Coord. Chem. 46, 411 (2020). https://doi.org/10.1134/S1070328420060056

    Article  CAS  Google Scholar 

  24. I. A. Lutsenko, D. S. Yambulatov, M. A. Kiskin, et al., Russ. J. Coord. Chem. 46, 787 (2020). https://doi.org/10.1134/S1070328420120040

    Article  CAS  Google Scholar 

  25. I. A. Lutsenko, M. A. Kiskin, K. A. Koshenskova, et al. Russ. Chem. Bull. 70, 463 (2021). https://doi.org/10.1007/s11172-021-3109-3

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

X-ray diffraction analysis of compound I was carried out using the equipment of the Center for Molecular Structure Studies of the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, and was supported by the Ministry of Science and Higher Education of the Russian Federation. Elemental analysis, STA, and IR spectroscopy were carried out using the equipment of the Center for Collective Use of Physical Methods of Investigation of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, which is supported by the state assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental research.

Funding

This study was performed within the state assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental research and programs of the Russian Academy of Sciences. X-ray diffraction analysis of compound I was supported by the by the Ministry of Science and Higher Education of the Russian Federation and was done using the equipment of the Center for Molecular Structure Studies of the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences.

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    M. E. Nikiforova, I. A. Lutsenko, M. A. Kiskin, A. V. Khoroshilov & I. L. Eremenko

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    Yu. V. Nelyubina & P. V. Primakov

  3. Vavilov Institute of General Genetics, Russian Academy of Sciences, 119991, Moscow, Russia

    O. B. Bekker

Authors
  1. M. E. Nikiforova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. A. Lutsenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. A. Kiskin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. V. Nelyubina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. P. V. Primakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. O. B. Bekker
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. V. Khoroshilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. I. L. Eremenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. E. Nikiforova.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by Z. Svitanko

Supplementary Information

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Nikiforova, M.E., Lutsenko, I.A., Kiskin, M.A. et al. Coordination Polymer of Ba2+ with 2-Furoic Acid Anions: Synthesis, Structure, and Thermal Properties. Russ. J. Inorg. Chem. 66, 1343–1349 (2021). https://doi.org/10.1134/S0036023621090102

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023621090102

Keywords:

Search

Navigation