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Impregnated Type Sorbents for Pb2+ Recovery from Neutral and Acidic Solutions

  • PHYSICAL CHEMISTRY OF SOLUTIONS
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Abstract

Synthetically convenient method for preparing phosphoryl podand 1,8-bis[2-(diphenylphosphorylmethyl)phenoxy]-3,6-dioxaoctane (L) has been developed. Recovery of Pb2+ with impregnated type sorbents was studied, the sorbents contain isodentate organic ligands—phosphoryl podand L and crown ether (4,4',(5')-di(tert-butyl)dicyclohexyl-18-crown-6)—as extractants. A sorbent based on the phosphoryl podand quantitatively extracts lead from neutral solutions (R = 98.4%) and does not recover it from acid solutions. On the contrary, the sorbents based on 4,4',(5')-di(tert-butyl)dicyclohexyl-18-crown-6 do not extract lead from neutral media and efficiently adsorb it from nitric and hydrochloric acid solutions (R = 90% from 3 M nitric acid solutions and R = 73.2% from 2 M hydrochloric acid solutions). Effect of diluent and support type, support pretreatment procedure, impregnation temperature and time, and solvent for support impregnation on lead sorption with sorbents based on 4,4',(5')-di(tert-butyl)dicyclohexyl-18-crown-6 have been studied.

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Funding

This work was supported by the Russian Foundation for Basic Research and the Government of Sevastopol city (project no. 18-43-920004 r_a), the Foundation for Promotion of Small Scientific and Technical Business (program Start-1, project no. S1-21807), by the Federal Agency of Scientific Organizations of Russian Federation (project no. 0827-2019-0003), and the Presidium of the RAS (program no. 14P).

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Authors and Affiliations

  1. Sevastopol State University , 299053, Sevastopol, Russia

    N. A. Bezhin

  2. Marine Hydrophysical Institute, Russian Academy of Sciences, 299011, Sevastopol, Russia

    I. I. Dovhyi

  3. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, 65080, Odessa, Ukraine

    A. Yu. Lyapunov

  4. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. E. Baulin, D. V. Baulin & A. Yu. Tsivadze

  5. Institute of Physiologically Active Substances, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    V. E. Baulin

Authors
  1. N. A. Bezhin
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  2. I. I. Dovhyi
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  3. A. Yu. Lyapunov
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  4. V. E. Baulin
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  5. D. V. Baulin
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  6. A. Yu. Tsivadze
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Corresponding authors

Correspondence to N. A. Bezhin or I. I. Dovhyi.

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Translated by I. Kudryavtsev

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Bezhin, N.A., Dovhyi, I.I., Lyapunov, A.Y. et al. Impregnated Type Sorbents for Pb2+ Recovery from Neutral and Acidic Solutions. Russ. J. Inorg. Chem. 64, 1178–1185 (2019). https://doi.org/10.1134/S0036023619090031

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  • DOI: https://doi.org/10.1134/S0036023619090031

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