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Selective precipitation of rare earth orthophosphates with hydrogen peroxide from phosphoric acid solutions

  • Synthesis and Properties of Inorganic Compounds
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Abstract

It has been shown for the first time that the use of hydrogen peroxide allows precipitation of rare earth orthophosphates (La–Tb) from phosphoric acid solutions at temperatures below 100°C. Either anhydrous or hydrated orthophosphates with monazite or rhabdophane structure, respectively, can be obtained depending on rare earth element position in lanthanide series and precipitation conditions (orthophosphoric acid and hydrogen peroxide concentration). Hydrated orthophosphates with rhabdophane structure can be prepared by precipitation with hydrogen peroxide for all studied rare earth elements.

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References

  1. S. Gai, C. Li, P. Yang, and J. Lin, Chem. Rev. 114, 2343 (2014).

    Article  CAS  Google Scholar 

  2. J. Shen, L.-D. Sun, and C.-H. Yan, Dalton Trans. 9226, 5687 (2008).

    Article  Google Scholar 

  3. J. F. Lima, P. C. De Sousa Filho, and O. A. Serra, Ceram. Int. 42, 7422 (2016).

    Article  CAS  Google Scholar 

  4. Y. X. Ni, J. M. Hughes, and A. N. Mariano, Am. Mineral. 80, 21 (1995).

    Article  CAS  Google Scholar 

  5. S. Sankar, B. N. Nair, T. Suzuki, et al., Sci. Rep. 6, 22732 (2016).

    Article  CAS  Google Scholar 

  6. I. McGill, Rare Earth Elements, in: Ullmann’s Encyclopedia of Industrial Chemistry (Wiley, Weinheim, 2000).

    Book  Google Scholar 

  7. M. Inoue, T. Nakamura, H. Otsu, et al., Nippon Kagaku Kaishi, 612 (1993).

  8. R. S. Hay, P. Mogilevsky, and E. Boakye, Acta Mater. 61, 6933 (2013).

    Article  CAS  Google Scholar 

  9. M. Kizilyalli and J. E. Welch, J. Appl. Crystallogr. 9, 413 (1976).

    Article  Google Scholar 

  10. K. S. Gavrichev, M. A. Ryumin, A. V. Khoroshilov, et al., Thermochim. Acta 641, 63 (2016).

    Article  CAS  Google Scholar 

  11. R. C. L. Mooney, Acta Crystallogr. 3, 337 (1950).

    Article  CAS  Google Scholar 

  12. H. Assaoudi and A. Ennaciri, Spectrochim. Acta A 53, 895 (1997).

    Article  Google Scholar 

  13. H. Assaaoudi, A. Ennaciri, and A. Rulmont, Vib. Spectrosc. 25, 81 (2001).

    Article  CAS  Google Scholar 

  14. W. Min, K. Daimon, T. Ota, et al., Mater. Res. Bull. 35, 2199 (2000).

    Article  CAS  Google Scholar 

  15. A. S. Vanetsev, E. V. Samsonova, O. M. Gaitko, et al., J. Alloys Compd. 639, 415 (2015).

    Article  CAS  Google Scholar 

  16. J. D. Donaldson, A. Hezel, and S. D. Ross, J. Inorg. Nucl. Chem. 29, 1239 (1967).

    Article  CAS  Google Scholar 

  17. H. Assaaoudi, A. Ennaciri, A. Rulmont, and M. Harcharras, Phase Transitions 72, 1 (2000).

    Article  CAS  Google Scholar 

  18. M. R. Rafiuddin and A. P. Grosvenor, Inorg. Chem. 55, 9685 (2016).

    Article  CAS  Google Scholar 

  19. S. Lucas, E. Champion, D. Bregiroux, et al., J. Solid State Chem. 177, 1302 (2004).

    Article  CAS  Google Scholar 

  20. Y. Zhang and H. Guan, J. Cryst. Growth 256, 156 (2003).

    Article  CAS  Google Scholar 

  21. P. Yang, Z. Quan, C. Li, et al., J. Solid State Chem. 182, 1045 (2009).

    Article  CAS  Google Scholar 

  22. D. Hudry, I. Bardez, A. Rakhmatullin, et al., J. Nucl. Mater. 381, 284 (2008).

    Article  CAS  Google Scholar 

  23. K. I. Bryukhanova, G. E. Nikiforova, and K. S. Gavrichev, Nanosyst. Phys. Chem. Math. 7, 451 (2016).

    Article  Google Scholar 

  24. Y. Fang, A. Xu, R. Song, et al., J. Am. Chem. Soc. 125, 16025 (2003).

    Article  CAS  Google Scholar 

  25. C. Yu, M. Yu, C. Li, et al., J. Solid State Chem. 182, 339 (2009).

    Article  CAS  Google Scholar 

  26. C. Li, Z. Hou, C. Zhang, et al., Chem. Mater. 21, 4598 (2009).

    Article  CAS  Google Scholar 

  27. L. S. Skogareva, T. O. Shekunova, A. E. Baranchikov, et al., Russ. J. Inorg. Chem. 61, 1219 (2016).

    Article  CAS  Google Scholar 

  28. D. E. Chirkst and O. V. Cheremisina, Zapiski Gornogo Instituta 169, 219 (2007).

    Google Scholar 

  29. I. A. Lebedev and Yu. M. Kulyako, Zh. Neorg. Khim. 23, 3215 (1978).

    CAS  Google Scholar 

  30. F. H. Firsching and S. N. Brune, J. Chem. Eng. Data 36, 93 (1991).

    Article  CAS  Google Scholar 

  31. M. E. de Vasconcellos, S. M. R. da Rocha, W. R. Pedreira, et al, J. Alloys Compd. 451, 426 (2008).

    Article  Google Scholar 

  32. L. A. Ovchar and N. S. Poluektov, Zh. Neorg. Khim. 26, 2364 (1981).

    CAS  Google Scholar 

  33. A. D. Yapryntsev, L. S. Skogareva, A. E. Gol’dt, et al. Russ. J. Inorg. Chem. 60, 1027 (2015).

    Article  CAS  Google Scholar 

  34. G. B. Deacon, C. M. Forsyth, D. Freckmann, et al., Aust. J. Chem. 67, 1860 (2014).

    Article  CAS  Google Scholar 

  35. W. J. Gee, J. G. MacLellan, C. M. Forsyth, et al., Inorg. Chem. 51, 8661 (2012).

    Article  CAS  Google Scholar 

  36. W. N. Hartley, J. Chem. Soc. Trans. 41, 202 (1882).

    Article  CAS  Google Scholar 

  37. E. M. Larsen and W. A. Cilley, J. Inorg. Nucl. Chem. 30, 287 (1968).

    Article  CAS  Google Scholar 

  38. T. O. Shekunova, A. E. Baranchikov, O. S. Ivanova, et al., J. Non-Cryst. Solids 447, 183 (2016).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    L. S. Skogareva, T. O. Shekunova, A. E. Baranchikov, O. S. Ivanova, A. D. Yapryntsev & V. K. Ivanov

  2. Mendeleev University of Chemical Technology of Russia, Moscow, 125047, Russia

    S. Yu. Kottsov

  3. Moscow State University, Moscow, 119991, Russia

    T. O. Shekunova & A. E. Baranchikov

  4. National Research Tomsk State University, Tomsk, 634050, Russia

    V. K. Ivanov

Authors
  1. L. S. Skogareva
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  2. S. Yu. Kottsov
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  3. T. O. Shekunova
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  4. A. E. Baranchikov
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  5. O. S. Ivanova
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  6. A. D. Yapryntsev
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  7. V. K. Ivanov
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Corresponding author

Correspondence to A. E. Baranchikov.

Additional information

Original Russian Text © L.S. Skogareva, S.Yu. Kottsov, T.O. Shekunova, A.E. Baranchikov, O.S. Ivanova, A.D. Yapryntsev, V.K. Ivanov, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 9, pp. 1145–1151.

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Skogareva, L.S., Kottsov, S.Y., Shekunova, T.O. et al. Selective precipitation of rare earth orthophosphates with hydrogen peroxide from phosphoric acid solutions. Russ. J. Inorg. Chem. 62, 1141–1146 (2017). https://doi.org/10.1134/S0036023617090157

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  • DOI: https://doi.org/10.1134/S0036023617090157

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