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Structural features of green cobalt(III) hydroxide

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Abstract

Emission Mössbauer and X-ray absorption XANES/EXAFS spectroscopic techniques are applied to elucidate the structural features of green cobalt(III) hydroxide. A comparative analysis of structurally characterized cobalt(II) and cobalt(III) oxo-compounds shows that the parameters of the local environment of cobalt atoms in green cobalt(III) hydroxide differ substantially from those of its analogues.

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References

  1. V. A. Shcherbinin and G. A. Bogdanov, Zh. Fiz. Khim. 32, 2761 (1958).

    CAS  Google Scholar 

  2. V. A. Shcherbinin and G. A. Bogdanov, Zh. Neorg. Khim. 4, 260 (1959).

    CAS  Google Scholar 

  3. N. G. Klyuchnikov, The Manual of Inorganic Synthesis (Khimiya, Moscow, 1965) [in Russian].

    Google Scholar 

  4. N. G. Klyuchnikov, Practical Work in Inorganic Synthesis (Prosveshchenie, Moscow, 1979) [in Russian].

    Google Scholar 

  5. N. G. Klyuchnikov, Inorganic Synthesis (Prosveshchenie, Moscow, 1983) [in Russian].

    Google Scholar 

  6. N. G. Klyuchnikov, Inorganic Synthesis (Prosveshchenie, Moscow, 1988) [in Russian].

    Google Scholar 

  7. I. G. Gorichev, B. E. Zaitsev, N. A. Kipriyanov, et al., The Manual of Inorganic Synthesis (Khimiya, Moscow, 1997) [in Russian].

    Google Scholar 

  8. J. A. Connor and E. A. V. Ebsworth, Adv. Inorg. Chem. Radiochem. 6, 279 (1964).

    Article  CAS  Google Scholar 

  9. L. Vaska, Acc. Chem. Res. 9, 175 (1976).

    Article  CAS  Google Scholar 

  10. Yu. I. Bratushko, Coordination Compounds of Transition Metals with Dioxygen (Naukova Dumka, Kiev, 1987) [in Russian].

    Google Scholar 

  11. J. S. Valentine, Chem. Rev. 73(3), 235 (1973).

    Article  CAS  Google Scholar 

  12. A. B. P. Lever and H. B. Gray, Acc. Chem. Res. 11, 348 (1978).

    Article  CAS  Google Scholar 

  13. G. McLendon, S. R. Pickens, and A. E. Martell, Inorg. Chem. 16, 1551 (1977).

    Article  CAS  Google Scholar 

  14. D. A. Pankratov, P. V. Prikhodchenko, Yu. D. Perfil’ev, and E. G. Ippolitov, Izv. Akad. Nauk, Ser. Fiz. 65, 1043 (2001).

    CAS  Google Scholar 

  15. D. A. Pankratov, A. I. Dement’ev, and Yu. M. Kiselev, Russ. J. Inorg. Chem. 53, 247 (2008).

    Article  Google Scholar 

  16. D. A. Pankratov, P. N. Komozin, and Yu. M. Kiselev, Russ. J. Inorg. Chem. 56, 1794 (2011).

    Article  CAS  Google Scholar 

  17. D. A. Pankratov, T. A. Portachenko, and Yu. D. Perfil’ev, Moscow Univ. Chem. Bull. 49, 292 (2008).

    Article  Google Scholar 

  18. Handbuch der praeparativen anorganischen Chemie, Ed. by G. Brauer (Ferdinand Enke, Stuttgart, 1981; Mir, Moscow, 1985), Vol. 3.

    Google Scholar 

  19. A. A. Chernyshov, A. A. Veligzhanin, and Y. V. Zubavichus, Nucl. Instr. Meth. Phys. Res. A 603, 95 (2009).

    Article  CAS  Google Scholar 

  20. M. Newville, J. Synch. Rad. 8, 322 (2001).

    Article  CAS  Google Scholar 

  21. F. Menil, J. Phys. Chem. Solids 46, 763 (1985).

    Article  CAS  Google Scholar 

  22. M. Deliens and H. Goethals, Mineral. Mag. 39, 152 (1973).

    Article  CAS  Google Scholar 

  23. F. Pertlik, Monatsh. Chem. Verw. Teile Anderer Wiss. 130, 1083 (1999).

    CAS  Google Scholar 

  24. F. Pertlik, Acta Crystallogr., Sect. C 42, 4 (1986).

    Article  Google Scholar 

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Correspondence to D. A. Pankratov.

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Original Russian Text © D.A. Pankratov, A.A. Veligzhanin, Y.V. Zubavichus, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 1, pp. 70–76.

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Pankratov, D.A., Veligzhanin, A.A. & Zubavichus, Y.V. Structural features of green cobalt(III) hydroxide. Russ. J. Inorg. Chem. 58, 67–73 (2013). https://doi.org/10.1134/S0036023613010142

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