Abstract
Emission Mössbauer and X-ray absorption XANES/EXAFS spectroscopic techniques are applied to elucidate the structural features of green cobalt(III) hydroxide. A comparative analysis of structurally characterized cobalt(II) and cobalt(III) oxo-compounds shows that the parameters of the local environment of cobalt atoms in green cobalt(III) hydroxide differ substantially from those of its analogues.
Similar content being viewed by others
References
V. A. Shcherbinin and G. A. Bogdanov, Zh. Fiz. Khim. 32, 2761 (1958).
V. A. Shcherbinin and G. A. Bogdanov, Zh. Neorg. Khim. 4, 260 (1959).
N. G. Klyuchnikov, The Manual of Inorganic Synthesis (Khimiya, Moscow, 1965) [in Russian].
N. G. Klyuchnikov, Practical Work in Inorganic Synthesis (Prosveshchenie, Moscow, 1979) [in Russian].
N. G. Klyuchnikov, Inorganic Synthesis (Prosveshchenie, Moscow, 1983) [in Russian].
N. G. Klyuchnikov, Inorganic Synthesis (Prosveshchenie, Moscow, 1988) [in Russian].
I. G. Gorichev, B. E. Zaitsev, N. A. Kipriyanov, et al., The Manual of Inorganic Synthesis (Khimiya, Moscow, 1997) [in Russian].
J. A. Connor and E. A. V. Ebsworth, Adv. Inorg. Chem. Radiochem. 6, 279 (1964).
L. Vaska, Acc. Chem. Res. 9, 175 (1976).
Yu. I. Bratushko, Coordination Compounds of Transition Metals with Dioxygen (Naukova Dumka, Kiev, 1987) [in Russian].
J. S. Valentine, Chem. Rev. 73(3), 235 (1973).
A. B. P. Lever and H. B. Gray, Acc. Chem. Res. 11, 348 (1978).
G. McLendon, S. R. Pickens, and A. E. Martell, Inorg. Chem. 16, 1551 (1977).
D. A. Pankratov, P. V. Prikhodchenko, Yu. D. Perfil’ev, and E. G. Ippolitov, Izv. Akad. Nauk, Ser. Fiz. 65, 1043 (2001).
D. A. Pankratov, A. I. Dement’ev, and Yu. M. Kiselev, Russ. J. Inorg. Chem. 53, 247 (2008).
D. A. Pankratov, P. N. Komozin, and Yu. M. Kiselev, Russ. J. Inorg. Chem. 56, 1794 (2011).
D. A. Pankratov, T. A. Portachenko, and Yu. D. Perfil’ev, Moscow Univ. Chem. Bull. 49, 292 (2008).
Handbuch der praeparativen anorganischen Chemie, Ed. by G. Brauer (Ferdinand Enke, Stuttgart, 1981; Mir, Moscow, 1985), Vol. 3.
A. A. Chernyshov, A. A. Veligzhanin, and Y. V. Zubavichus, Nucl. Instr. Meth. Phys. Res. A 603, 95 (2009).
M. Newville, J. Synch. Rad. 8, 322 (2001).
F. Menil, J. Phys. Chem. Solids 46, 763 (1985).
M. Deliens and H. Goethals, Mineral. Mag. 39, 152 (1973).
F. Pertlik, Monatsh. Chem. Verw. Teile Anderer Wiss. 130, 1083 (1999).
F. Pertlik, Acta Crystallogr., Sect. C 42, 4 (1986).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © D.A. Pankratov, A.A. Veligzhanin, Y.V. Zubavichus, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 1, pp. 70–76.
The article was translated by the authors.
Rights and permissions
About this article
Cite this article
Pankratov, D.A., Veligzhanin, A.A. & Zubavichus, Y.V. Structural features of green cobalt(III) hydroxide. Russ. J. Inorg. Chem. 58, 67–73 (2013). https://doi.org/10.1134/S0036023613010142
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036023613010142