Skip to main content
SpringerLink
Log in

Supported MgO–V2O5/Al2O3 catalysts for oxidative propane dehydration: Effect of the molar Mg : V ratio on the phase composition and catalytic properties of samples

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The physicochemical properties of V2O5/Al2O3 and MgO–V2O5/Al2O3 supported catalysts (Mg : V = 1 : 1, 2 : 1, and 3 : 2) obtained by consecutive impregnation of the support with solutions of vanadium and magnesium precursors are studied using a complex of mutually complementary methods (XRD, Raman spectroscopy, UV–Vis spectrometry, and TPR-H2). The effect of the formation of surface magnesium vanadates of various composition and structure on the catalytic properties of the supported vanadium oxide catalysts in the oxidative dehydrogenation of propane is studied. The introduction of magnesium in the samples and an increase in its content, accompanied by a change in the structure of the surface vanadium oxide phases from polymeric VO6/VO5 species to surface metavanadate species, magnesium metavanadate, and further to magnesium divanadate, significantly affects their catalytic properties in the reaction of the oxidative dehydrogenation of propane to propylene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Cavani, F., Ballarini, N., and Cericola, A., Catal. Today, 2007, vol. 127, p. 113.

    Article  CAS  Google Scholar 

  2. Cavani, F. and Trifiro, F., Appl. Catal., A, 1995, vol. 133, p. 219.

    Article  CAS  Google Scholar 

  3. Buyevskaya, O.V. and Baerns, M., Catalysis, 2002, vol. 16, p. 155.

    Article  CAS  Google Scholar 

  4. Sattler, J.H.B., Ruiz-Martinez, J., Santillan-Jimenez, E., and Weckhuysen, B.M., Chem. Rev., 2014, vol. 114, p. 10613.

    Article  CAS  Google Scholar 

  5. Mukherjee, D., Park, S.-E., and Reddy, B.M., J. CO2 Utilization, 2016, vol. 16, p. 301.

    Article  CAS  Google Scholar 

  6. Carrero, C.A., Keturakis, C.J., Orrego, A., Schomäcker, R., and Wachs, I.E., Dalton Trans., 2013, vol. 42, p. 12644.

    Article  CAS  Google Scholar 

  7. Carrero, C.A., Schloegl, R., Wachs, I.E., and Schomaecker, R., ACS Catal., 2014, vol. 4, p. 3357.

    Article  CAS  Google Scholar 

  8. Mamedov, E.A. and Cortes-Corberan, V., Appl. Catal., A, 1995, vol. 127, p. 1.

    Article  CAS  Google Scholar 

  9. Alexopoulos, K., Reyniers, M.F., and Marin, G.J., J. Catal., 2012, vol. 289, p. 127.

    Article  CAS  Google Scholar 

  10. Rozanska, X., Fortrie, R., and Sauer, J., J. Phys. Chem. C, 2007, vol. 111, p. 6041.

    Article  CAS  Google Scholar 

  11. Nguyen, N.H., Tran, T.H., Nguyen, M.T., and Le, M.C., Int. J. Quantum Chem., 2010, vol. 110, p. 2653.

    Article  CAS  Google Scholar 

  12. Lio, Y., Feng, W., Li, T., He, H., Dai, W., Huang, W., Cao, Y., and Fan, K.-N., J. Catal., 2006, vol. 239, p. 125.

    Article  Google Scholar 

  13. Chalupka, K., Thomas, C., Millot, Y., Averseng, F., and Dzwigaj, S., J. Catal., 2013, vol. 305, p. 46.

    Article  CAS  Google Scholar 

  14. Kumar, A.S.H., Upendar, K., Qiao, A., Rao, P.S.N., Lingaiah, N., Kalevaru, V.N., Martin, A., Sailu, Ch., and Sai-Prasad, P.S., Catal. Commun., 2013, vol. 33, p. 76.

    Article  CAS  Google Scholar 

  15. Reddy, B.M., Rao, K.N., Reddy, G.K., Khan, A., and Park, S.-E., J. Phys. Chem. C, 2007, vol. 111, p. 18751.

    Article  CAS  Google Scholar 

  16. Klisińska, A., Samson, K., Gressel, I., and Grzybowska, B., Appl. Catal., A, 2006, vol. 309, p. 10.

    Article  Google Scholar 

  17. Vislovskiy, V.P., Shamilov, N.Y., Sardarly, A.M., Bychkov, V.Yu., Sinev, M.Yu., Ruiz, P., and Valenzuela, R.X., Cortes corberan v, Chem. Eng. J., 2003, vol. 95, p. 37.

    CAS  Google Scholar 

  18. Ayandiran, A., Bakare, I.A., Binous, H., Al-Ghamdi, S., Razzak, S., and Hossain, M.M., Catal. Sci. Technol., 2016, vol. 6, p. 5154.

    Article  CAS  Google Scholar 

  19. Yang, S., Iglesia, E., and Bell, A.T., J. Phys. Chem. B, 2005, vol. 109, p. 8987.

    Article  CAS  Google Scholar 

  20. Dai, H., Bell, A.T., and Iglesia, E., J. Catal., 2004, vol. 221, p. 491.

    Article  CAS  Google Scholar 

  21. Carrero, C., Kauer, M., Dinse, A., Wolfram, T., Hamilton, N., Trunschke, A., Schlögl, R., and Schomäcker, R., Catal. Sci. Technol., 2014, vol. 4 P, p. 786.

    Article  CAS  Google Scholar 

  22. Vidal-Michel, R. and Hochn, K.L., J. Catal., 2004, vol. 221, p. 127.

    Article  CAS  Google Scholar 

  23. Hanuza, J., Jeż owska-Trzebiatowska, B., and Oganowski, W., J. Mol. Catal., 1985, vol. 29, p. 109.

    Article  CAS  Google Scholar 

  24. Chang, W.S., Chen, Y.Z., and Yang, B.L., Appl. Catal., A, 1995, vol. 124, p. 221.

    Article  CAS  Google Scholar 

  25. Pless, J.D., Bardin, B.B., Kim, H.-S., Ko, D., Smith, M.T., Hamond, R.R., Stair, P.C., and Poeppelmeier, K.R., J. Catal., 2004, vol. 223, p. 419.

    Article  CAS  Google Scholar 

  26. Soenen, V., Herrmann, J.M., and Voltay, J.C., J. Catal., 1996, vol. 159, p. 410.

    Article  CAS  Google Scholar 

  27. Dias, A.P.S., Dmitrov, L.D., and Oliveira, M.C.-R., Zavoianu, R., Fernandes, A., and Portela, M.F., J. Non-Cryst. Solids, 2010, vol. 356, p. 1488.

    Article  Google Scholar 

  28. Lee, J.K., Hong, U.G., Yoo, Y., Cho, Y.-J., Lee, J., Chang, H., Song, I.K., and Nanosci, J., Nanotecnology, 2013, vol. 13, p. 8110.

    CAS  Google Scholar 

  29. Ogonowski, J. and Skrzyńska, E., Catal. Lett., 2006, vol. 111, p. 79.

    Article  CAS  Google Scholar 

  30. Machli, M., Heracleous, E., and Lemonidou, A.A., Appl. Catal., A, 2002, vol. 236, p. 23.

    Article  CAS  Google Scholar 

  31. Machli, M. and Lemonidou, A.A., Catal. Lett., 2005, vol. 99, p. 221.

    Article  CAS  Google Scholar 

  32. Kharlamova, T., Sushchenko, E., Izaak, T., and Vodyankina, O., Catal. Today, 2016, vol. 278, p. 174.

    Article  CAS  Google Scholar 

  33. Lever, A.B.P., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1984.

    Google Scholar 

  34. Berndt, H., Martin, A., Brü ckner, A., Schreier, E., Müller, D., Kosslick, H., Wolf, G.-U., and Lücke, B., J. Catal., 2000, vol. 191, p. 384.

    Article  CAS  Google Scholar 

  35. Centi, G., Perathoner, S., Triifiro, F., Aboukais, A., Aissi, C.F., and Guelton, M., J. Phys. Chem., 1992, vol. 96, p. 2617.

    Article  CAS  Google Scholar 

  36. Morey, M., Davidson, A., Eckert, H., and Stucky, G., Chem. Mater., 1996, vol. 8, p. 486.

    Article  CAS  Google Scholar 

  37. Ng, H.N. and Calvo, C., Can. J. Chem., 1972, vol. 50, p. 3619.

    Article  Google Scholar 

  38. Gao, X. and Wachs, I.E., J. Phys. Chem. B, 2000, vol. 104, p. 1261.

    Article  CAS  Google Scholar 

  39. Liu, Y.-M., Feng, W.-L., Li, T.-C., He, H.-Y., Dai, W.-L., Huang, W., Cao, Y., and Fan, K.-N., J. Catal., 2006, vol. 239, p. 125.

    Article  CAS  Google Scholar 

  40. Gao, X., Bare, S.R., Weckhuysen, B.M., and Wachs, I.E., J. Phys. Chem. B, 1998, vol. 102, p. 10842.

    Article  CAS  Google Scholar 

  41. Wachs, I.E., Dalton Trans., 2013, vol. 42, p. 11762.

    Article  CAS  Google Scholar 

  42. Deo, C. and Wachs, I.E., J. Phys. Chem., 1991, vol. 95, p. 5895.

    Article  Google Scholar 

  43. Busca, G., Ricchiard, G., Sam, D.S.H., and Volta, J.-C., J. Chem. Soc., Faraday Trans., 1994, vol. 90, p. 1161.

    Article  CAS  Google Scholar 

  44. Jin, M. and Chen, Z.-M., Catal. Lett., 2009, vol. 131, p. 266.

    Article  CAS  Google Scholar 

  45. Sugiyama, S., Hashimoto, T., Shigemoto, N., and Hayashia, H., Catal. Lett., 2003, vol. 89, nos. 3–4, p. 229.

    Article  CAS  Google Scholar 

  46. Kijima, N., Toba, M., and Yoshimura, Y., Catal. Lett., 2003, vol. 127, p. 63.

    Article  Google Scholar 

  47. Sugiyama, S., Hirata, Y., Nakagawa, K., Sotowa, K.-I., Maehara, K., Himeno, Y., and Ninomiya, W., J. Catal., 2008, vol. 260, p. 157.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Tomsk State University, Tomsk, 634050, Russia

    E. D. Sushchenko, T. S. Kharlamova, T. I. Izaak & O. V. Vodyankina

Authors
  1. E. D. Sushchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. S. Kharlamova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. I. Izaak
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. V. Vodyankina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. S. Kharlamova.

Additional information

Original Russian Text © E.D. Sushchenko, T.S. Kharlamova, T.I. Izaak, O.V. Vodyankina, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 5, pp. 642–653.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sushchenko, E.D., Kharlamova, T.S., Izaak, T.I. et al. Supported MgO–V2O5/Al2O3 catalysts for oxidative propane dehydration: Effect of the molar Mg : V ratio on the phase composition and catalytic properties of samples. Kinet Catal 58, 630–641 (2017). https://doi.org/10.1134/S0023158417050202

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158417050202

Keywords

Search

Navigation