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Coordination compound of samarium(III) with acylhydrazone of N-(2-hydroxyphenyl)iminodiacetic acid and 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole

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Abstract

The structure of a samarium(III) complex with acylhydrazone of N-(2-hydroxyphenyl)iminodiacetic acid and 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole (Н5L) of the composition [Sm2(Н3L)3]·С2Н5ОН··10Н2О has been determined by single crystal X-ray diffraction. It has been found that in the dinuclear complex the coordination polyhedra have the geometry of a slightly distorted tri-capped trigonal prism and are linked with three iminodimethylene bridges arranged in a triple helix.

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Authors and Affiliations

  1. Vernadsky Crimean Federal University, Simferopol, Crimea Republic, Russia

    V. F. Shul’gin & Z. Z. Bekirova

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    G. G. Aleksandrov & I. L. Eremenko

Authors
  1. V. F. Shul’gin
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  2. Z. Z. Bekirova
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  3. G. G. Aleksandrov
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  4. I. L. Eremenko
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Corresponding author

Correspondence to V. F. Shul’gin.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 8, pp. 1782–1785, November–December, 2016.

Original Russian Text © 2016 V. F. Shul’gin, Z. Z. Bekirova, G. G. Aleksandrov, I. L. Eremenko.

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Shul’gin, V.F., Bekirova, Z.Z., Aleksandrov, G.G. et al. Coordination compound of samarium(III) with acylhydrazone of N-(2-hydroxyphenyl)iminodiacetic acid and 5-hydroxy-3-methyl-1-phenyl-4-formylpyrazole. J Struct Chem 57, 1684–1687 (2016). https://doi.org/10.1134/S002247661608028X

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  • DOI: https://doi.org/10.1134/S002247661608028X

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