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A coordination network constructed by heteroleptic Co(II) complex built upon intermolecular hydrogen bonds: Synthesis and characterization

  • Self-Organization in Molecular and Supramolecular Compounds
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Abstract

A new mixed ligand complex of Co(II), [Co(pydc)(2-apym)(H2O)2]·H2O (1) (pydcH2=pyridine-2,6-dicarboxylic acid, 2-apym=2-aminopyrimidine) has been synthesized and characterized by CHN micro analysis, IR and UV spectroscopies, TGA and single crystal X-ray diffraction. The crystallographic data show that the compound 1 crystallizes in monoclinic system with P21/c space group. In the title compound, Co(II) is six-coordinated with a distorted octahedral geometry made up by tridenate (pydc)2−, monodentate 2-apym coordinated via an N atom of the pyrimidine ring and two coordinated water molecules. The discrete complex molecules are aggregated by O2-H2A⋯O108 and N206-H20B⋯O107 hydrogen bonds and create a double chain 1-D coordination network

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Authors and Affiliations

  1. Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, Mashhad, 917791436, I. R. Iran

    H. Eshtiagh-Hosseini & Z. Yousefi

  2. Department of Chemistry, Durham University, Durham, DH1 3LE, UK

    H. Puschmann

Authors
  1. H. Eshtiagh-Hosseini
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  2. Z. Yousefi
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  3. H. Puschmann
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Correspondence to H. Eshtiagh-Hosseini.

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Original Russian Text © 2014 H. Eshtiagh-Hosseini, Z. Yousefi, H. Puschmann.

The text was submitted by the authors in English.

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Eshtiagh-Hosseini, H., Yousefi, Z. & Puschmann, H. A coordination network constructed by heteroleptic Co(II) complex built upon intermolecular hydrogen bonds: Synthesis and characterization. J Struct Chem 55, 1607–1615 (2014). https://doi.org/10.1134/S0022476614080307

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  • DOI: https://doi.org/10.1134/S0022476614080307

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