Abstract
A metal-organic framework, Fe-BDC, was synthesized by solvothermal method from iron salt and terephthalic acid using N,N-dimethylformamide as the solvent. The data from the study of structural-energy characteristics calculated by the Dubinin-Radushkevich, Kelvin, and BET equations are given. The resulting Fe-BDC sample has a specific surface area of SBET = 2240 m2/g and a specific micropore volume of W0 = 0.83 cm3/g. The morphological and X-ray characteristics of this sample were studied.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Uzun, A. and Keskin, S., Prog. Surf. Sci., 2014, vol. 89, p. 56.
Llewellyn, P.L., Bourrelly, S., Serre, C., et al., Langmuir, 2008, vol. 24, p. 7245.
Krishna, R. and Baten, J.M., Sep. Purif. Technol., 2012, vol. 87, p. 120.
Alhamami, M., Doan, H., and Cheng, C.-H., Materials, 2014, vol. 7, p. 3198.
Sabouni, R., Kazemian, H., and Rohani, S., Environ. Sci. Pollut. Res. Int., 2014, vol. 21, p. 5427.
Zhao, D., Yuan, D., and Zhou, H.-C., Energy Environ. Sci., 2008, vol. 1, p. 222.
Sculley, J., Yuan, D., and Zhou, H.-C., Energy Environ. Sci., 2011, vol. 4, p. 2721.
Falcaro, P., Ricco, R., Doherty, C.M., Liang, K., et al., Chem. Soc. Rev., 2014, vol. 43, p. 5513.
Howarth, J., Liu, Y., Li, P., et al., Nat. Rev. Mater., 2016, vol. 1, p. 15 018.
Agustaa, M.K., Saputroa, A.G., Tanuwijayaa, V.V., et al., Procedia Eng., 2017, vol. 170, p. 136.
Kayal, S., Sun, B., and Chakraborty, A., Energy, 2015, vol. 91, p. 772.
Chowdhury, P., Bikkina, C., and Gumma, S., J. Phys. Chem. C, 2009, vol. 113, p. 6616.
Hong, D.Y., Hwang, Y.K., Serre, C., et al., Adv. Funct. Mater., 2009, vol. 19, p. 1537.
Horcajada, P., Chevreau, H., Heurtaux, D., et al., Chem. Commun., 2014, vol. 50, p. 6872.
Senkovska, I., Hoffmann, F., Fröba, M., Kaskel, S., et al., Microporous Mesoporous Mater., 2009, vol. 122, p. 93.
Kel’tsev, N.V., Osnovy adsorbtsionnoi tekhniki (Foundations of Adsorption Technique), Moscow: Khimiya, 1976.
Dubinin, M.M., Adsorbtsiya i poristost' (Adsorption and Porosity), Moscow: Military Academy of Chemical Defense Named after Marshal of the USSR S.K. Timoshenko, 1972.
Eksperimental'nye metody v adsorbtsii i molekulyarnoi khromatografii (Experimental Methods for Adsorption and Molecular Chromatography), Kiselev, A.V. and Dreving, V.P., Eds., Moscow: Moscow State Univ., 1973.
Shiryaev, A.A., Voloshchuk, A.M., Volkov, V.V., et al., J. Phys., 2017, vol. 848, p. 012009.
Zhigalina, V., Zhigalina, O., Ponomarev, I., et al., CrystEngComm, 2017, vol. 19, p. 3792.
Shkolin, A.V. and Fomkin, A.A., Measurement Techniques, 2018, vol. 61, pp. 395–401.
Ferey, G., Mellot-Draznieks, C., Serre, C., et al., Science, 2005, vol. 309, p. 2040.
Kholdeeva, O.A., Skobelev, I.Y., Ivanchikova, I.D., et al., Catal. Today, 2014, vol. 238, p. 54.
Taylor-Pashow, K.M.L., Xie, Z., Tran, S., et al., J. Am. Chem. Soc., 2009, vol. 131, p. 14261.
Vemuri, R.S., Armatis, P.D., Bontha, J.R., et al., J. Bioterrorism Biodef., 2015, vol. 6, p. 137.
ACKNOWLEDGMENTS
The contribution of the Center for Collective Use of Physical Methods of Investigation (Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences) is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by K. Utegenov
Rights and permissions
About this article
Cite this article
Knyazeva, M.K., Shkolin, A.V., Fomkin, A.A. et al. Synthesis and Structural-Energy Characteristics of Fe-BDC Metal-Organic Frameworks. Prot Met Phys Chem Surf 54, 1004–1009 (2018). https://doi.org/10.1134/S2070205118060151
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2070205118060151