Skip to main content
SpringerLink
Log in

Electrochemical synthesis of polypyrrole on aluminium in different anions and corrosion protection of aluminium

  • New Substances, Materials and Coatings
  • Published:
Protection of Metals and Physical Chemistry of Surfaces Aims and scope Submit manuscript

Abstract

In this study, polypyrrole was deposited on the aluminium in different anions (CO 2−3 , NO −2 , CrO 2−4 , DBS−). The contribution of anions to formation of polypyrrole film was investigated by using cyclic voltammetry (CV) technique. The effect of polypyrrole film on the corrosion of aluminium was searched in 0.1 M HCI solution by using potentiostatic method. For this purpose, polarization curves were obtained, corrosion current density (icorr), corrosion potential (Ecorr), polarization resistance (Rp) were determined from the polarization curves. Moreover, the percent efficiency of coating was calculated. The complexes of pyrrole pentamers and different anions (CO 2−3 , NO −2 , CrO 2−4 , DBS−) were studied using ab initio quantum chemical at the Hartree-Fock (HF) levels with STO-3G, 3-21G, 6-31G(d,p) [13] basis sets and HOMO-LUMO energy gap is calculated by B3LYP method with 3-21G* and 6-31G(d,p) basis sets. The polypyrrole film obtained in CrO 2−4 anion is determined to be the most effective in prevention to pitting corrosion of aluminium as experimental and theoretical.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Huerta-Vilca, D., Retina de Moraes, S., and Jesus Motheo, A., J. Solid State Electrochem., 2005, vol. 9, P. 416.

    Article  CAS  Google Scholar 

  2. Conroy, K.G. and Breslin, C.B., Electrochim. Acta, 2003, vol. 48, p. 721.

    Article  CAS  Google Scholar 

  3. Smitha Akundy, G. and Iroh, J.O., Polymer., 2001, vol. 42, p. 9665.

    Article  Google Scholar 

  4. Beck, F. and Hülser, P., J. Electroanal. Chem., 1990, vol. 280, p. 159.

    Article  CAS  Google Scholar 

  5. Hülser, P. and Beck, F., J. Apply. Electrochem., 1990, vol. 20, p. 596.

    Article  Google Scholar 

  6. Naoi, K., Takeda, M., and Kano, H., et al., Electrochim. Acta., 2000, vol. 45, p. 3413.

    Article  CAS  Google Scholar 

  7. Saidman, S.B. and Bessone, J.B., J. Electroanal. Chem., 2002, vol. 521, p. 87.

    Article  CAS  Google Scholar 

  8. Zor, S. and Yakar, E., J.Chem. Soc. Pak (in press).

  9. Kousik, G., Pitchumani, S., and Renganathan, N.G., Prog. Org. Coat., 2001, vol. 43, p. 286.

    Article  CAS  Google Scholar 

  10. Tuken, T., Yazici, B., and Erbil, M., Surface and Coatings Technology, vol. 200(16–17), p. 4802.

  11. Lee, K., Yang, K., and Kwak, J., Electrochem. Comm., 2002, vol. 4, p. 128.

    Article  CAS  Google Scholar 

  12. Hien, N.T.L., Garcia, B., Pailleret, A., and Deslouis, C., Electrochim. Acta, 2005, vol. 50, p. 1747.

    Article  CAS  Google Scholar 

  13. Osaka, T., Naoi, K., Sakai, H., and Ogano, S., J. Electrochem. Soc., 1987, vol. 134, p. 285.

    Article  CAS  Google Scholar 

  14. Kanamura, K., Kawai, Y., Yonezawa, S., and Takehara, Z., J. Phys. Chem., 1994, vol. 98, p. 2174.

    Article  CAS  Google Scholar 

  15. Johanson, U., Marandi, M., Tamm, T., and Tamm, J., Electrochim. Acta, 2005, vol. 50, p. 1523.

    Article  CAS  Google Scholar 

  16. Conroy, K.G. and Breslin, C.B., J. Appl. Electrochem., 2004, vol. 34, p. 191.

    Article  CAS  Google Scholar 

  17. Branzoi, F., Mol. Cryst. Liq. Cryst., vol. 416, p. 73.

  18. Naoi, K., Takeda, M., Kano, H., et al., Electrochim. Acta, 2000, vol. 45, p. 3413.

    Article  CAS  Google Scholar 

  19. Fenelon, A.M. and Breslin, C.B., Synthetic Metals, 2004, vol. 144, p. 125.

    Article  CAS  Google Scholar 

  20. Kendig, M., Jeanjaquet, S., Addison, R., and Waldrop, J., Surface @& Coatings Technology, 2001, vol. 140, p. 58.

    Article  CAS  Google Scholar 

  21. Kendig, M., Davenport, A., and Isaacs, H., Corrosion Sci., 1993, vol. 34(1), p. 41.

    Article  CAS  Google Scholar 

  22. Tamm, J., Raudsepp, T., Marandi, M., and Tamm, T., Synthetic Metals, 2007, vol. 157, p. 66.

    Article  CAS  Google Scholar 

  23. Rabias, L. and Howlin, B.J., Polymer Science, vol. 11, p. 241.

  24. Johanson, U., Marandi, M., Tamm, T., and Tamm, J., Electrochim. Acta, 2005, vol. 50, p. 1523.

    Article  CAS  Google Scholar 

  25. Frisch, M.J., Trucks, G.W., Schlegel, K.B., et al., Gaussian 03, Revision B.05., Wallingford CT: Gaussian, Inc., 2004.

    Google Scholar 

  26. McLean, A.D. and Chandler, G.S., J. Chem. Phys., 1980, vol. 72, p. 5639.

    Article  CAS  ADS  Google Scholar 

  27. McGrath, M.P. and Radom, L., J. Chem. Phys., 1991, vol. 94, p. 511.

    Article  CAS  ADS  Google Scholar 

  28. Bartlett, R.J., Ann. Rev. Phys. Chem., 1981, vol. 32, p. 359.

    Article  CAS  Google Scholar 

  29. Young, D.C., A Practical Guide for Applying Techniques to Real-World Problems Computational Chemistry, N.Y.: John Wiley & Sons, Inc., 2001.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemistry Department, Kocaeli University Science & Art Faculty, 41380, Kocaeli, Turkey

    S. Zor, F. Kandemirli & E. Yakar

  2. Science&Art Faculty, Chemistry Department, Eskisehir Osmangazi University, 26480, Eskisehir, Turkey

    T. Arslan

Authors
  1. S. Zor
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. F. Kandemirli
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Yakar
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. Arslan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Zor.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zor, S., Kandemirli, F., Yakar, E. et al. Electrochemical synthesis of polypyrrole on aluminium in different anions and corrosion protection of aluminium. Prot Met Phys Chem Surf 46, 110–116 (2010). https://doi.org/10.1134/S2070205110010168

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070205110010168

Keywords

Search

Navigation