Skip to main content
Log in

General Regularities and Features of Photodegradation of Polyphenylene Sulfide Modified by Ethylene and Glycidyl–Methacrylate Copolymer

  • Published:
Polymer Science, Series D Aims and scope Submit manuscript

Abstract

The influence of the spectral composition of light, temperature, and modifier content on the formation of polyconjugated structures and oxidation products upon irradiation of a composite based on polyphenylene sulfide has been studied by quantitative colorimetry and IR spectroscopy. The extent of the change in color and the amount of oxygen-containing groups under successive irradiation with total radiation and visible light, as well as irradiation and thermal exposure, are estimated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Yu. A. Mikhailin, Heat Resistant Polymers and Polymeric Materials (Professiya, St. Petersburg, 2006) [in Russian].

    Google Scholar 

  2. A. S. Rahate, K. R. Nemade, and S. A. Waghuley, “Polyphenylene sulfide (PPS): state of the art and applications,” Rev. Chem. Eng. 29, 471–489 (2013).

    Article  CAS  Google Scholar 

  3. T. Smmazçelik, “Natural weathering effects on the mechanical and surface properties of polyphenylene sulfide (PPS) composites,” Mater. & Design 17, 270–277 (2006).

    Article  Google Scholar 

  4. Z. Yu, L. Li, S. Meng, L. Chen, et al., “Effect of TiO2@SiO2 nanoparticles on the mechanical and UV-resistance properties of polyphenylene sulfide fiber,” Progr. Nat. Sci.: Mater. Int. 25, 310–315 (2015).

    Article  Google Scholar 

  5. K. B. Mahat, I. Alarifi, A. Alharbi, et al., “Effects of UV Light on the Mechanical Properties of Carbon Fiber Reinforced PPS Thermoplastic Composites,” Macromolecular Symposia 365, 157– 168 (2016).

    Article  CAS  Google Scholar 

  6. V. B. Ivanov, V. V. Bitt, E. V. Solina, and V. A. Samoryadov, “Reversible and irreversible color change during photo and thermal degradation of polyphenylene sulfide composite,” Polymers, No. 1579 (2019).

  7. V. B. Ivanov, E. V. Solina, and A. V. Samoryadov, “The effect of irradiation conditions on photodegradation of impact resistant polyphenylene sulfide-based composite,” Polym. Sci., Ser. D 13, 353–357 (2020).

    CAS  Google Scholar 

  8. X. Z. Zhang, K. Zhang, Z. Zhou, et al., “Preparation of radiation-resistant high performance polyphenylene sulfide fiber with improved processing,” Procedia Eng. 27, 1354–1358 (2012).

    Article  CAS  Google Scholar 

  9. X. Yang, L. Duan, and X. Ran, “Effect of polydopamine coating on improving photostability of polyphenylene sulfide fiber,” Polymer Bull. 74, 641–656 (2017).

    Article  CAS  Google Scholar 

  10. A. V. Samoryadov, E. V. Kalugina, and E. S. Usenko, RF Patent No. 2741907 (2021).

  11. R. Steffen, M. Meir, J. Rekstad, et al., “Kinetic of degradation induced polymer luminescence: a polyphenylene sulfide/elastomer blend under dry heat exposure,” Polymer 136, 71–83 (2018).

    Article  CAS  Google Scholar 

  12. CIE 15.32004. CIE Technical Report: Colorimetry, 3rd ed., p. 17.

  13. V. B. Ivanov and E. V. Solina, “The influence of temperature on photodegradation of colored polymers,” Polym. Sci., Ser. D 12, 100–104 (2019).

    CAS  Google Scholar 

  14. V. B. Ivanov, E. V. Solina, O. V. Staroverova, et al., “Influence of external condition on the relation between the physical and chemical processes in the thermodegradation of plasticized poly(vinyl chloride),” Russ. J. Phys. Chem. B 11, 978–984 (2017).

    Article  CAS  Google Scholar 

  15. V. B. Ivanov, E. V. Solina, and E. I. Popova, “Colorimetric analysis of thermal degradation of plasticized poly (vinyl chloride): potentials and limitations,” Polym. Sci., Ser. B 59, 348–353 (2017).

    Article  CAS  Google Scholar 

Download references

Funding

This work was performed in the framework of a state order of the Ministry of Science and Higher Education of the Russian Federation, no. 122040500069-7.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. B. Ivanov.

Additional information

Translated by K. Aleksanyan

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ivanov, V.B., Solina, E.V. & Usachev, S.V. General Regularities and Features of Photodegradation of Polyphenylene Sulfide Modified by Ethylene and Glycidyl–Methacrylate Copolymer. Polym. Sci. Ser. D 15, 472–478 (2022). https://doi.org/10.1134/S1995421222030108

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1995421222030108

Keywords:

Navigation