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Macromolecular-chain rearrangement during synthesis of poly(N-phenylurethanes)

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Abstract

Poly(N-phenyliminocarbonates) capable of converting into poly(N-phenylurethanes) via thermal treatment at 300°C for 9 h through the Chapman mechanism were prepared via the polycondensation of bisphenols with plenyliminophosgene. The resulting polymers are soluble in chlorinated hydrocarbons and amide solvents. The polymers are characteristic by glass-transition and 10%-weight-loss temperatures during heating in air of 165–210 and 455–490°C, respectively.

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Authors and Affiliations

  1. Baikal Institute for Nature Management, Siberian Branch, Russian Academy of Sciences, ul. Marii Sakh”yanovoi 6, Ulan-Ude, 670047, Buryatia, Russia

    V. F. Burdukovskii & D. M. Mognonov

Authors
  1. V. F. Burdukovskii
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  2. D. M. Mognonov
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Correspondence to V. F. Burdukovskii.

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Original Russian Text © V.F. Burdukovskii, D.M. Mognonov, 2013, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2013, Vol. 55, No. 4, pp. 475–479.

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Burdukovskii, V.F., Mognonov, D.M. Macromolecular-chain rearrangement during synthesis of poly(N-phenylurethanes). Polym. Sci. Ser. B 55, 213–217 (2013). https://doi.org/10.1134/S1560090413040015

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  • DOI: https://doi.org/10.1134/S1560090413040015

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