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On the approximate estimation of the surface tension of chalcogenide glass melts

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Abstract

The surface tension coefficients of chalcogenide glasses are estimated. It is demonstrated that, to a first approximation, the results of the existing techniques for estimating the surface tension coefficients of chalcogenide glasses are in satisfactory agreement. The energies of formation of fluctuation microvoids in chalcogenide glasses according to the calculations from data on the surface tension and the density agree with the results obtained by the conventional method from data on the glass transition temperature and the fraction of the fluctuation free volume.

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References

  1. Mott, N.F. and Davis, E.A., Electronic Processes in Non-Crystalline Materials, Oxford: Clarendon, 1971. Translated under the title Elektronnye protsessy v nekristallicheskikh veshchestvakh, Moscow: Mir, 1974.

    Google Scholar 

  2. Sanditov, D.S. and Bartenev, G.M., Fizicheskie svoistva neuporyadochennykh struktur (Physical Properties of Disordered Structures), Novosibirsk: Nauka, 1982 [in Russian].

    Google Scholar 

  3. Kikineshi, A.A. and Mel’nichenko, T.N., Parameters of the Free Volume Theory as Applied to the Model of Photoinduced Changes in the Properties of Chalcogenide Glasses, in Proceedings of the XV International Congress on Glass, Leningrad, Russia, 1989, Leningrad: Nauka, 1989, pp. 66–69.

    Google Scholar 

  4. Skripov, V.P. and Koverda, V.P., Spontannaya kristallizatsiya pereokhlazhdennykh zhidkostei (Spontaneous Crystallization of Supercooled Liquids), Moscow: Nauka, 1984 [in Russian].

    Google Scholar 

  5. Turnbull, D. and Cohen, M.H., Crystallization Kinetics and Glass Formation, in Modern Aspects of the Vitreous State, Mackenzie, J.D., Ed., London: Butterworths, 1960, vol. 1, pp. 38–46.

    Google Scholar 

  6. Frenkel, Ya.I., Kineticheskaya teoriya zhidkosti (The Kinetic Theory of Liquid), Leningrad: Nauka, 1975 [in Russian].

    Google Scholar 

  7. Frenkel, Ya.I., Vvedenie v teoriyu metallov (Introduction to the Theory of Metals), Moscow: OGIZ, 1948 [in Russian].

    Google Scholar 

  8. Hoffman, J.D., Thermodynamic Driving Force in Nucleation and Growth Processes, J. Chem. Phys., 1958, vol. 29, no. 5, pp. 1192–1193.

    Article  ADS  CAS  Google Scholar 

  9. Hollomon, J.H. and Turnbull, D., Nucleation, in Progress in Metal Physics, 1953, vol. 4, pp. 333–388. Translated under the title Uspekhi fiziki metallov, Moscow: Metallurgizdat, 1956, vol. 1.

    Article  ADS  CAS  Google Scholar 

  10. Temkin, D.E., On the Growth Rate of the Needle Crystal in a Supercooled Melt, Dokl. Akad. Nauk SSSR, 1960, vol. 132, no. 6, pp. 1307–1310.

    Google Scholar 

  11. Feltz, A., Amorphe und glasartige anorganische Festk[umlaut]orper, Berlin: Akademie, 1983. Translated under the title Amorfnye i stekloobraznye neorganicheskie tverdye tela, Moscow: Mir, 1986.

    Google Scholar 

  12. Bainova, A.B., Sanditov, B.D., Badmaev, S.S., and Sangadiev, S.Sh., Calculation of the Surface Tension Coefficient for Silicate Glasses in the Framework of the Hole Model, Fiz. Khim. Stekla, 1999, vol. 25, no. 6, pp. 699–702 [Glass Phys. Chem. (Engl. transl.), 1999, vol. 25, no. 6, pp. 529–531].

    Google Scholar 

  13. Coenen, M., Sprung im Ausdehnungskoeffizienten und Leerstellenkonzentration bei T g von glasigen Systemen, Glastech. Ber., 1977, vol. 50, no. 4, pp. 74–78.

    CAS  Google Scholar 

  14. Sanditov, D.S. and Sangadiev, S.Sh., Condition of Glass Transition in the Fluctuation Free Volume Theory and the Lindemann Criterion for Melting, Fiz. Khim. Stekla, 1998, vol. 24, no. 4, pp. 417–420 [Glass Phys. Chem. (Engl. transl.), 1998, vol. 24, no. 4, pp. 285–294].

    Google Scholar 

  15. Sanditov, D.S. and Sangadiev, S.Sh., A New Approach to Interpretation of the Fluctuation Free Volumes of Amorphous Polymers and Glasses, Vysokomol. Soedin., Ser. A, 1999, vol. 41, no. 6, pp. 977–100 [Polym. Sci., Ser. A (Engl. transl.), 1999, vol. 41, no. 6, pp. 643–663].

    CAS  Google Scholar 

  16. Mel’nichenko, T.N., Kutsenko, Ya.P., Fedelesh, V.I., Yurkin, I.M., and Mel’nichenko, T.D., Interrelation between the Glass Transition Temperature, Thermal Expansion Coefficient, and Poisson Ratio for Some Glasses in the AV-BVI-CVII Systems, Fiz. Khim. Stekla, 2001, vol. 27, no. 4, pp. 449–458 [Glass Phys. Chem. (Engl. transl.), 2001, vol. 27, no. 4, pp. 298–305].

    Google Scholar 

  17. Mel’nichenko, T.N., Fedelesh, V.I., Yurkin, I.M., and Mel’nichenko, T.D., Application of the Free Volume Concept to Glasses in the Ge-As-S System, Fiz. Khim. Stekla, 2002, vol. 28, no. 1, pp. 39–49 [Glass Phys. Chem. (Engl. transl.), 2002, vol. 28, no. 1, pp. 25–32].

    Google Scholar 

  18. Mel’nichenko, T.D., Rizak, V.M., Mel’nichenko, T.N., and Fedelesh, V.I., Parameters of the Free Volume Theory for Semiconductor Glasses in the Ge-As(Sb)-S and Cd-As Systems, Fiz. Khim. Tverd. Tila, 2004, vol. 5, no. 1, pp. 663–671.

    Google Scholar 

  19. Mel’nichenko, T.D., Rizak, V.M., Mel’nichenko, T.N., and Fedelesh, V.I., Parameters of the Fluctuation Free Volume Theory for Glasses in the Ge-As-Se System, Fiz. Khim. Stekla, 2004, vol. 30, no. 5, pp. 553–564 [Glass Phys. Chem. (Engl. transl.), 2004, vol. 30, no. 5, pp. 406–414].

    Google Scholar 

  20. Nemilov, S.V. and Petrovskii, G.T., Investigation of the Viscosity of Glasses in the Selenium-Arsenic System, Zh. Prikl. Khim. (Leningrad), 1963, vol. 36, no. 4, pp. 977–981.

    CAS  Google Scholar 

  21. Nemilov, S.V., Viscosity and Structure of Glasses in the Selenium-Germanium System, Zh. Prikl. Khim. (Leningrad), 1964, vol. 37, no. 5, pp. 1020–1024.

    CAS  Google Scholar 

  22. Nemilov, S.V., Viscosity and Structure of Glasses in the As-Ge-Se System in the Range of a Low Selenium Content, Zh. Prikl. Khim. (Leningrad), 1964, vol. 37, no. 8, pp. 1699–1708.

    CAS  Google Scholar 

  23. Nemilov, S.V., Viscosity and Structure of Glasses in the As-Ge-Se System in the Range of a High Selenium Content, Zh. Prikl. Khim. (Leningrad), 1964, vol. 37, no. 7, pp. 1452–1457.

    CAS  Google Scholar 

  24. Nemilov, S.V., The Viscosity and Elastic Properties of Glasses and Melts in the As-S System and Their Valence Structure, Fiz. Khim. Stekla, 1979, vol. 5, no. 4, pp. 398–409.

    CAS  Google Scholar 

  25. Poltavtsev, Yu.G., Struktura poluprovodnikovykh rasplavov (Structure of Semiconductor Melts), Moscow: Metallurgiya, 1986 [in Russian].

    Google Scholar 

  26. Turyanitsa, I.D., Mel’nichenko, T.N., Shtets, P.P., and Rubish, V.M., Glass Formation, Structure, and Properties of Alloys in the Sb-S-I System, Izv. Akad. Nauk SSSR, Neorg. Mater., 1986, vol. 22, no. 12, pp. 2047–2051.

    CAS  Google Scholar 

  27. Shkol’nikov, E.V., Semiempirical Calculations of the Tammann Curves for Crystallization of As2 X 3 and TlAsX (X = S, Se, Te) Glasses, Fiz. Khim. Stekla, 1980, vol. 6, no. 3, pp. 282–291.

    MathSciNet  Google Scholar 

  28. Kikineshi, A.A., Mel’nichenko, T.N., and Batori, K.A., Photostructural Transformations with Local Ordering in Chalcogenide Glass Layers, in Tezisy dokladov vsesoyuznogo nauchno-tekhnicheskogo seminara “Strukturnye prevrashcheniya i relaksatsionnye yavleniya v nekristallicheskikh tverdykh telakh” (Abstracts of Papers of the All-Union Scientific and Technical Workshop “Structural Transformations and Relaxation Phenomena in Noncrystalline Solids”), Lvov-Drogobych, 1990, p. 43.

  29. Aio, L.G. and Kokorina, V.F., Glass Formation and Properties of Glasses in the As-Ge-Se System, Opt.-Mekh. Prom-st., 1963, no. 2, pp. 36–43.

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Correspondence to T. N. Mel’nichenko.

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Original Russian Text © T.D. Mel’nichenko, V.I. Fedelesh, T.N. Mel’nichenko, D.S. Sanditov, S.S. Badmaev, D.G. Damdinov, 2009, published in Fizika i Khimiya Stekla.

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Mel’nichenko, T.D., Fedelesh, V.I., Mel’nichenko, T.N. et al. On the approximate estimation of the surface tension of chalcogenide glass melts. Glass Phys Chem 35, 32–42 (2009). https://doi.org/10.1134/S1087659609010052

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