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Reactivity of co-micellar systems based on dimeric functionalized tetraalkylammonium surfactant in phosphoryl and sulfonyl group transfer processes

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Abstract

The reactivity of co-micellar systems based on dimeric functionalized tetraalkylammonium surfactant in phosphoryl and sulfonyl group transfer processes is lower than the reactivity of systems based on analogous imidazolium surfactant. The observed difference in the kinetics of acyl group transfer promoted by dimeric surfactants differing by the nature of the cationic center is likely to be general, and it results from both different nucleophilicities of their oximate fragments and different modes of solubilization of hydrophobic substrates. The most probable reasons for the latter are differences in intramolecular Coulomb interactions and packing of surfactant molecules in co-micelles.

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Authors and Affiliations

  1. Litvinenko Institute of Physical Organic and Coal Chemistry, ul. R. Lyuksemburg 70, Donetsk, 83114, Ukraine

    T. M. Prokop’eva, M. L. Kostrikin, M. K. Turovskaya & N. G. Razumova

  2. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    I. V. Kapitanov, I. A. Belousova, A. E. Shumeiko & A. A. Serdyuk

Authors
  1. T. M. Prokop’eva
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  2. I. V. Kapitanov
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  3. I. A. Belousova
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  4. A. E. Shumeiko
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  5. M. L. Kostrikin
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  6. A. A. Serdyuk
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  7. M. K. Turovskaya
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  8. N. G. Razumova
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Corresponding author

Correspondence to M. K. Turovskaya.

Additional information

Original Russian Text © T.M. Prokop’eva, I.V. Kapitanov, I.A. Belousova, A.E. Shumeiko, M.L. Kostrikin, A.A. Serdyuk, M.K. Turovskaya, N.G. Razumova, 2017, published in Zhurnal Organicheskoi Khimii, 2017, Vol. 53, No. 4, pp. 503–506.

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Prokop’eva, T.M., Kapitanov, I.V., Belousova, I.A. et al. Reactivity of co-micellar systems based on dimeric functionalized tetraalkylammonium surfactant in phosphoryl and sulfonyl group transfer processes. Russ J Org Chem 53, 510–513 (2017). https://doi.org/10.1134/S1070428017040029

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  • DOI: https://doi.org/10.1134/S1070428017040029

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