Abstract
N-[arylsulfonylimino(methyl)methyl] derivatives of 1,4-benzoquinone monoimine with alkyl substituents in the quinoid ring have been synthesized and their spectral characteristics were determined. The thiocyanation of N-aryl, N-acetyl, and N-[arylsulfonylimino(methyl)methyl] derivatives of 1,4-benzoquinone monoimine depending on the LUMO energy of the initial quinone monoamine affords derivatives of benzo[d][1,3]oxathiol-2-ones and benzo[d]oxazole-2(3H)-thiones.
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Original Russian Text © S.A. Konovalova, A.P. Avdeenko, O.P. Ledeneva, A.L. Yusina, V.V. Pirozhenko, O.V. Shishkin, G.V. Palamarchuk, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 5, pp. 650–660.
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Konovalova, S.A., Avdeenko, A.P., Ledeneva, O.P. et al. Thiocyanation of N-aryl, N-acetyl, and N-[arylsulfonylimino(methyl)methyl] derivatives of 1,4-benzoquinone monoimine. Russ J Org Chem 50, 635–646 (2014). https://doi.org/10.1134/S1070428014050042
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DOI: https://doi.org/10.1134/S1070428014050042